• Article dans une revue

Vanadium-Substituted Phosphomolybdic Acids for the Aerobic Cleavage of Lignin Models-Mechanistic Aspect and Extension to Lignin

Louay Al-Hussaini, Franck Launay, Elena Galvez

This work deals with the aerobic oxidative cleavage of CC and CO bonds catalyzed by the Keggin-type phosphovanadomolybdic acid (H 6 [PMo 9 V 3 O 40 ], noted H 6 PV 3). The latter was synthesized by an adapted hydrothermal procedure classically used for lower vanadium content and was tested as a…

Materials, 2020, 13 (4), pp.812. ⟨10.3390/ma13040812⟩. ⟨hal-02553354⟩

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Dimerization of Uracil in a simulated Mars-like UV radiation environment

Laura Rouquette, Fabien Stalport, Hervé Cottin, Cyril Colas, Thomas Georgelin, Naïla Chaouche-Mechidal, Jerome Lasne, Sara Mahfouf, Franćois Raulin, Laura Selliez, Cyril Szopa, Patrice Coll

The search for organic molecules at the surface of Mars is a key objective in astrobiology, given that many organic compounds are possible biosignatures and their presence is of interest with regard to the habitability of Mars. Current environmental conditions at the martian surface are harsh and…

Astrobiology, 2020, 20 (11), pp.1363-1376. ⟨10.1089/ast.2019.2157⟩. ⟨hal-03032302⟩

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High-Current-Density CO2-to-CO Electroreduction on Ag-Alloyed Zn Dendrites at Elevated Pressure

Sarah Lamaison, David Wakerley, Juliette Blanchard, David Montero, Gwenaelle Rousse, Dimitri Mercier, Philippe Marcus, Dario Taverna, Domitille Giaume, Victor Mougel, Marc Fontecave

High-surface-area Ag-Zn-alloyed electrodes undertake the rapid conversion of CO 2 to CO. This has the combined benefit of removing CO 2 and producing an industrially relevant chemical synthon. At atmospheric pressure, the electrodes plateau in activity owing to the mass-transport limitation of CO 2…

Joule, 2020, 4 (2), pp.395-406. ⟨10.1016/j.joule.2019.11.014⟩. ⟨hal-02919030⟩

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Nanostructured Nickel Aluminate as a Key Intermediate for the Production of Highly Dispersed and Stable Nickel Nanoparticles Supported within Mesoporous Alumina for Dry Reforming of Methane

Leila Karam, Julien Reboul, Nissrine El Hassan, Jaysen Nelayah, Pascale Massiani

Molecules, 2019, 24 (22), pp.4107. ⟨10.3390/molecules24224107⟩. ⟨hal-03054098⟩

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Optimization of Synthesis Conditions of Ni/SBA-15 Catalysts: Confined Nanoparticles and Improved Stability in Dry Reforming of Methane

Nissrine El Hassan, Marie-Nour Kaydouh, Nissrine El, Anne Davidson, Pascale Massiani

Despite its economic and environmental advantages, the dry reforming of methane using supported Ni-based catalysts remains challenging due to problems of metal particle sintering and carbon deposition, which lead to loss in catalytic activity. In this study, different silica supports, containing 5…

Catalysts, 2020, 11 (1), pp.44. ⟨10.3390/catal11010044⟩. ⟨hal-03146326⟩

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Ni/CeO2 Nanoparticles Promoted by Yttrium Doping as Catalysts for CO2 Methanation

Valeria La Parola, Chao Sun, Patricia Beaunier, Leonarda F Liotta, Patrick da Costa

Ni (5 wt.%) catalysts over yttrium modified CeO2 oxides synthesized by hydrothermal method were prepared. For comparison Ni was supported over pure CeO2 and Y2O3. Characterizations by N2 adsorption/desorption, XRD, XPS, TEM/HRTEM, H2-TPR, CO2-TPD and TGA were carried out. The catalytic performance…

ACS Applied Nano Materials, 2020, 3 (12), pp.12355-12368. ⟨10.1021/acsanm.0c02841⟩. ⟨hal-03146777⟩

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Simultaneous removal of microorganisms and ethyl acetate from fruit storage indoor air using a low-cost photoreactor based on luminous textiles

Sarra Karoui, Amine Aymen Assadi, Amina Meslem, Bouzaza Abdelkrim

Escherichia coli ( E. coli), ), Salmonella typhimurium ( S. typhimurium), ), Listeria monocytogenes (L. monocytogenes), and Cladosporium cladosporioides (C. C. cladosporioides), ), as microorganisms, and ethyl acetate (EA), as a volatile organic compound, were chosen as target pollutants to be…

Food Bioscience, 2024, 61, pp.104771. ⟨10.1016/j.fbio.2024.104771⟩. ⟨hal-04699894⟩

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Impact of sorbitol addition on the structure and performance of silica-supported cobalt catalysts for Fischer-Tropsch synthesis

Hong Jingping, Eric Marceau, Andrei Y. Khodakov, Anne Griboval-Constant, Camille La Fontaine, Françoise Villain, Valérie Briois, P.A. Chernavskii

The paper focuses on the impact of sorbitol addition on the genesis of cobalt active phases in silica-supported catalysts and on their performance in Fischer-Tropsch synthesis. The catalysts were characterized by ex situ and in situ diffuse reflectance spectroscopy in the ultraviolet and visible…

Catalysis Today, 2011, 175 (1), pp.Pages 528-533. ⟨10.1016/j.cattod.2011.03.007⟩. ⟨hal-00663000⟩

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BEA zeolite modified with iron as effective catalyst for N2O decomposition and selective reduction of NO with ammonia

Pawel Boron, Lucjan Chmielarz, J. Gurgul, K. Łątka, Tetsuya Shishido, J.M. Krafft, Stanislaw Dzwigaj

BEA zeolite is modified by a two-steps postsynthesis method allowing incorporate iron atoms into the zeolite framework. Two series of the zeolite samples with aluminium (FexAlSiBEA) and without aluminium (FexSiBEA), containing various iron content (0.5-4.0 Fe wt.%) are obtained. For low Fe content…

Applied Catalysis B: Environmental, 2013, 138-139, pp.434-445. ⟨10.1016/j.apcatb.2013.03.022⟩. ⟨hal-00911026⟩

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Remarkable activity of Ag/Al2O3/cordierite catalysts in SCR of NO with ethanol and butanol

Pavlo Kyriienko, Nataliia Popovych, Sergiy Soloviev, Svitlana Orlyk, Stanislaw Dzwigaj

Structured silver-alumina catalysts were prepared by the one-step deposition of Al2O3 directly on the surface of cordierite block matrices with subsequent incipient wetness impregnation of Al2O3/cordierite with an AgNO3 aqueous solution. The catalysts were characterized by BET, XRD, XPS and FTIR…

Applied Catalysis B: Environmental, 2013, 140-141, pp.691-699. ⟨10.1016/j.apcatb.2013.04.067⟩. ⟨hal-00911716⟩