• Article dans une revue

Enhancing the magnetic anisotropy of maghemite nanoparticles via the surface coordination of molecular complexes

Yoann Prado, Niéli Daffé, Aude Michel, Thomas Georgelin, Nader Yaacoub, Jean-Marc Greneche, Fadi Choueikani, Edwige Otero, Philippe Ohresser, Marie-Anne Arrio, C. Cartier Dit Moulin, Ph. Sainctavit, Benoit Fleury, Vincent Dupuis, Laurent Lisnard, Jérôme Fresnais

Superparamagnetic nanoparticles are promising objects for data storage or medical applications. In the smallest—and more attractive—systems, the properties are governed by the magnetic anisotropy. Here we report a molecule-based synthetic strategy to enhance this anisotropy in sub-10-nm…

Nature Communications, 2015, 6, pp.10139. ⟨10.1038/ncomms10139⟩. ⟨hal-01390543⟩

• Article dans une revue

Design and Analytical Performances of a Diclofenac Biosensor for Water Resources Monitoring

Yacine Mazouzi, Antoine Miche, Alexis Loiseau, Bruno Beito, Christophe Méthivier, Dietmar Knopp, Michèle Salmain, Souhir Boujday

Because the broadly consumed pain killer diclofenac (DCF) is a recognized pollutant, monitoring of its concentration is routinely performed in surface waters. As a valuable alternative to chromatographic and immunochemical assays, we developed a piezoelectric immunosensor to quantify DCF, first in…

ACS Sensors, 2021, 6 (9), pp.3485-3493. ⟨10.1021/acssensors.1c01607⟩. ⟨hal-03351021⟩

• Article dans une revue

Evolution Mechanisms of T91 Steel in Subcritical Conditions and Role of an Internal Oxidation Zone

Seifallah Fetni, David Montero, Chokri Boubahri, Dalil Brouri, Jalel Briki

Corrosion of a T91 steel tube, used in subcritical conditions in an oil power plant for 157,000 h, was characterized mainly through SEM, TEM, EDX and DRX analyses. Severe oxidation and carburization took place in both the outer (boiler) and inner (steam) wall sides. The nature and morphology of the…

Oxidation of Metals, 2018, 90 (3-4), pp.291-315. ⟨10.1007/s11085-018-9837-6⟩. ⟨hal-04020418⟩

• Article dans une revue

Dual Thermo- and pH-Responsive N -Cyanomethylacrylamide-Based Nano-Objects Prepared by RAFT-Mediated Aqueous Polymerization-Induced Self-Assembly

Nicolas Audureau, Fanny Coumes, Jean-Michel Guigner, Clément Guibert, François Stoffelbach, Jutta Rieger

We report the straightforward synthesis of dual stimuli-responsive nano-objects using a RAFT-mediated polymerization-induced self-assembly (PISA) process in water. The key to complex and tunable responsiveness was the copolymerization of N-cyanomethylacrylamide, providing UCST-type polymers, with a…

Macromolecules, 2022, 55 (24), pp.10993-11005. ⟨10.1021/acs.macromol.2c01953⟩. ⟨hal-03988200⟩

• Article dans une revue

Biosensing Extracellular Vesicle Subpopulations in Neurodegenerative Disease Conditions

Yacine Mazouzi, Fadoua Sallem, Francesca Farina, Alexis Loiseau, Natayme Rocha Tartaglia, Morgane Fontaine, Atul Parikh, Michèle Salmain, Christian Neri, Souhir Boujday

ACS Sensors, 2022, 7 (6), pp.1657-1665. ⟨10.1021/acssensors.1c02658⟩. ⟨hal-03791750⟩

• Article dans une revue

Investigating the Mukaiyama-type epoxidation reaction of alkenes with Cr(III) salophen catalysts: A confrontation between experiments and DFT calculations

Arnaud Marvilliers, Jean-Baptiste Harlé, Franck Launay, Sébastien Blanchard, Anne Gauvin-Bialecki, Hélène Gérard, Richard Villanneau

This study aimed at the complete elucidation of the mechanism of the Mukaiyama-type alkene epoxidation reaction using the [(salophen)CrIIICl] precatalyst, by combining spectroscopic (UV–visible and EPR) studies, catalytic reactivity and quantum chemical modeling. These studies performed in parallel…

Journal of Catalysis, 2024, 434, pp.115526. ⟨10.1016/j.jcat.2024.115526⟩. ⟨hal-04579211⟩

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Simple procedure for vacant POM-stabilized palladium (0) nanoparticles in water: structural and dispersive effects of lacunary polyoxometalates

Richard Villanneau, A. Roucoux, P. Beaunier, D. Brouri, A. Proust

Metallic palladium nanoparticles have been generated by hydrogenation in very mild conditions of aqueous solutions of non-organometallic PdII-derivatives of heteropolytungstates.

RSC Advances, 2014, 4 (50), pp.26491-26498. ⟨10.1039/C4RA03104K⟩. ⟨hal-04564836⟩

• Article dans une revue

Investigation of an Allergen Adsorption on Amine- and Acid-Terminated Thiol Layers: Influence on Their Affinity to Specific Antibodies

P. Thebault, Souhir Boujday, Helene Senechal, Claire-Marie Pradier

This work describes the controlled immobilization of a recognized allergen, beta-lactoglobulin, onto gold transducers with the aim of optimizing the elaboration of a biosensor directed against allergen-produced antibodies. This protein was immobilized on both amine- and acid-terminated thiol self-…

Journal of Physical Chemistry B, 2010, 114 (32), pp.10612-10619. ⟨10.1021/jp103164b⟩. ⟨hal-00604802⟩

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Acidic Osteoid Templates the Plywood Structure of Bone Tissue

Marc Robin, Chakib Djediat, Arnaud Bardouil, Niki Baccile, Camille Chareyron, Ivo Zizak, Peter Fratzl, Mohamed Selmane, Bernard Haye, Isabelle Genois, Jean‐marc Krafft, Guylène Costentin, Thierry Azaïs, Franck Artzner, Marie‐madeleine Giraud-Guille, Paul Zaslansky, Nadine Nassif

Bone is created by osteoblasts that secrete osteoid after which an ordered texture emerges, followed by mineralization. Plywood geometries are a hallmark of many trabecular and cortical bones, yet the origin of this texturing in vivo has never been shown. Nevertheless, extensive in vitro work…

Advanced Science, 2023, pp.2304454. ⟨10.1002/advs.202304454⟩. ⟨hal-04384750⟩

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Increasing the efficiency of magnetic heterogeneous Fenton catalysts with a simple halogen visible lamp

Nassira Ferroudj, Delphine Talbot, Aude Michel, Anne Davidson, Sébastien Abramson

The effect of a simple visible halogen lamp was studied in the Fenton-type oxidation of three model aqueous pollutants differing in their structure and electrostatic charge, methylorange (MO), methylene blue (MB) and paranitrophenol (PNP), using maghemite nanoparticles (γ-Fe 2 O 3 NP), or maghemite…

Journal of Photochemistry and Photobiology A: Chemistry, 2017, 338, pp.85-95. ⟨10.1016/j.jphotochem.2017.01.029⟩. ⟨hal-01525893⟩