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  • Article dans une revue

Recent development of heterogeneous catalysis in ring-opening, biocatalysis, and selective partial oxidation reactions on metal oxides

Ioana Fechete, Jacques C. Védrine

In this review article, we analyze the state of the art and future developments in three important domains of heterogeneous catalysis, namely ring opening, biocatalysis, and partial oxidation on metal oxides. After recollecting the scientific bases of each domain, we consider several examples, some…

Comptes Rendus. Chimie, 2018, 21 (3-4), pp.408 - 418. ⟨10.1016/j.crci.2017.12.005⟩. ⟨hal-01761420⟩

  • Article dans une revue

Exploring the reactivity of mixed omega-functionalized undecanethiol self-assembled monolayers - A DFT study

Frederik Tielens, Vincent Humblot, Claire-Marie Pradier

The reactive sites of self-assembled monolayers (SAM) formed by substituted thiolalkyl chains have been predicted in the case of the pure mercaptoundecane acid, for the pure mercaptoundecane alcohol, and the mixed 1:1 SAMs. The differences in reactivity between the different SAM domains (pure and…

International Journal of Quantum Chemistry, 2008, 108 (10), pp.1792-1795. ⟨10.1002/qua.21600⟩. ⟨hal-01361371⟩

  • Article dans une revue

Covalent immobilization of glucose oxidase on mesocellular silica foams: Characterization and stability towards temperature and organic solvents

Noemie Balistreri, Dorian Gaboriau, Claude Jolivalt, Franck Launay

Glucose oxidase (GOx) immobilization onto mesoporous SBA-15 silica and two mesocellular foams (MCF) characterized by similar surface area and pore volumes but different pore/cell dimensions was examined. The covalent grafting of the enzyme through amide bonds was evidenced by controlling pH…

Journal of Molecular Catalysis B: Enzymatic, 2016, 127, pp.26-33. ⟨10.1016/j.molcatb.2016.02.003⟩. ⟨hal-01281753⟩

  • Article dans une revue

Dynamics of Hydration in Vanadia-Titania Catalysts at Low Loading: A Theoretical and Experimental Study

Anna E. Lewandowska, Monica Catalayud, Frederik Tielens, Miguel A. Banares

The hydration process of dehydrated vanadia-titania catalysts at low loading is investigated using periodic DFT calculations. We focus on the early stages of the hydration process of the vanadia-titania in order to shed light onto the structural and dynamical changes occurring at the molecular…

Journal of Physical Chemistry C, 2011, 115, pp.24133-24142. ⟨10.1021/jp204726b⟩. ⟨hal-00669737⟩

  • Article dans une revue

A comparative study of the catalysis of peptide bonds formation by oxide surfaces

Jean-Francois Lambert, Maguy Jaber, Thomas Georgelin, Lorenzo Stievano

It is well-known that amino acids deposited on some inorganic oxides undergo peptidic condensation. It is seldom realised however that a large diversity of behaviours can be observed in such systems. Here we use the apparently simple case of glycine-non-porous silica as a reference system, in which…

Physical Chemistry Chemical Physics, 2013, 15 (32), pp.13371-13380. ⟨10.1039/C3CP51282G⟩. ⟨hal-00924129⟩

  • Article dans une revue

Ruthenium sulfide clusters in acidic zeolites: in situ XAS characterization during sulfidation and reaction

Juliette Blanchard, Kyoko K. Bando, Takashi Matsui, Masaru Harada, Michèle Breysse, Yuji Yoshimura

In situ XAS at the Ru K edge was used to study the reductive sulfidation (15% H2S/H2) of Ru(NH3)63+ supported on HYd zeolite, and the evolution of the sulfided sample under working conditions (lower H2S partial pressure, addition of toluene to the feed). Sulfidation starts at room temperature and…

Applied Catalysis A : General, 2007, XX, pp.XX. ⟨hal-00112011⟩

  • Communication dans un congrès

In situ XAFS study of the thioresistance of metallic Ru supported on HYd zeolite

Juliette Blanchard, K. Kyoko Bando, Christophe Geantet, Takashi Matsui, Michèle Breysse, Yuji Yoshimura

In situ XAFS at the Ru K edge was used to investigate the reduction of Ru(NH3)63+ supported on HYd zeolite, and the evolution of the reduced sample in the presence of sulfur (350 ppm and 2%H2S/H2) at 523K. After reduction at 673K very small Ru° nanoparticules are formed which interact strongly with…

TOCAT5, Jul 2006, Tokyo, Japan. ⟨hal-00112012⟩

  • Article dans une revue

Giant Exchange-Bias in Polyol-Made CoFe2O4-CoO Core-Shell Like Nanoparticles

Nancy Flores-Martinez, Giulia Franceschin, Thomas Gaudisson, Patricia Beaunier, Nader Yaacoub, Jean-Marc Greneche, Raul Valenzuela, Souad Ammar

Cobalt ferrite ferrimagnetic nanoparticles (NPs) are prepared and used in this work as seeds to grow a thin antiferromagnetic poly- and nanocrystalline CoO shell. The major purpose is to study systematically the characteristics of the as-produced powders, making emphasis on their internal…

Particle & Particle Systems Characterization, 2018, 35 (11), pp.1800290. ⟨10.1002/ppsc.201800290⟩. ⟨hal-02114586⟩

  • Article dans une revue

Catalytic behaviour of hybrid LNT/SCR systems: Reactivity and in situ FTIR study

L. Castoldi, R. Bonzi, L. Lietti, P. Forzatti, S. Morandi, G. Ghiotti, S. Dzwigaj

The NOx storage-reduction over the single Pt-Ba/Al2O3 and Fe-ZSM-5 systems and over the hybrid Pt-Ba/Al2O3 + Fe-ZSM-5 systems, both physically mixed and in dual bed configuration with the SCR catalyst placed downstream of the LNT catalyst, is systematically investigated by Isothermal Step…

Journal of Catalysis, 2011, 282, pp.128-144. ⟨10.1016/j.cat.2011.06.002⟩. ⟨hal-00664960⟩

  • Article dans une revue

Identification of the silver state in the framework of Ag-containing zeolite by XRD, FTIR, photoluminescence, 109 Ag NMR, EPR, DR UV-vis, TEM and XPS investigations

Nataliia Popovych, Pavlo Kyriienko, Sergiy Soloviev, Rafal Baran, Yannick Millot, Stanislaw Dzwigaj

Silver has been identified in the framework of AgxSiBEA zeolites (where x = 3–6 Ag wt%) by the combined use of XRD, 109Ag MAS NMR, FTIR, diffuse reflectance UV-visible, EPR and XPS spectroscopy. The incorporation of Ag ions into the framework of SiBEA zeolite has been evidenced by XRD. The…

Physical Chemistry Chemical Physics, 2016, 18, pp.29458-29465. ⟨10.1039/c6cp05263k⟩. ⟨hal-01387417⟩