Laboratoire de réactivité de surface

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  • Article dans une revue

A TEM and UV-visible study of silver reduction by ethanol in Ag-alumina catalysts

Elie Sayah, Dalil Brouri, Yiaho Wu, Andrea Musa, Patrick da Costa, Pascale Massiani

A transmission electron microscopy (TEM) study dedicated to the understanding of dispersion and location of Ag nanospecies in silver-alumina catalysts is reported. A special attention is put on the conditions of powder catalyst deposition on the grids for TEM analysis. When the deposition is…

Applied Catalysis A : General, 2011, 406, pp.94-101. ⟨10.1016/j.apcata.2011.08.016⟩. ⟨hal-00668908⟩

  • Article dans une revue

Extension of a kinetic model for NO oxidation and NOx storage to fixed-bed Pt/Ba/Al2O3 catalysts

Nikola Rankovic, Andre Nicolle, David Berthout, Patrick da Costa

Following our work on modeling of monolith catalysts, we herein focus on developing a fixed-bed reactor model in the AMESim modeling platform. A kinetic model for NO oxidn. and NOx storage over Pt/Ba/Al2O3 recently developed in the literature was successfully implemented and validated against the…

Catalysis Communications, 2010, 12 (1), pp.54-57. ⟨10.1016/j.catcom.2010.07.012⟩. ⟨hal-00604793⟩

  • Article dans une revue

Light olefin transformation over ZSM-5 zeolites with different acid strengths - A kinetic model

P. Oliveira, P. Borges, R. Ramos Pinto, M. A. N. D. A. Lemos, F. Lemos, Jacques C. Vedrine, F. Ramoa Ribeiro

The authors analyzed the influence of the acidity of a ZSM-5 catalyst on the catalytic transformation of various short-chain olefins (ethylene, propylene and 1-butene). Four ZMS-5 catalysts with different acid strength distributions were studied at different temps. and partial pressures. The…

Applied Catalysis A : General, 2010, 384 (1-2), pp.177-185. ⟨10.1016/j.apcata.2010.06.032⟩. ⟨hal-00604786⟩

  • Article dans une revue

NMR cogwheel phase cycling determination with web tools: Amplitude-modulated z-filter MQMAS sequence

Yannick Millot, Redouane Hajjar, Pascal P. Man

Our recent method based on the use of web tools (XML and XSLT) for constructing cogwheel phase cycles is extended to the selection of two sym. coherence transfer pathways in the case of an amplitude-modulated z-filter MQMAS sequence. For all spins (I=3/2, 5/2, 7/2 and 9/2) and all MQ expts. we…

Solid State Nuclear Magnetic Resonance, 2010, 38 (1), pp.19-26. ⟨10.1016/j.ssnmr.2010.06.001⟩. ⟨hal-00604781⟩

  • Article dans une revue

Role of the Al source in the synthesis of aluminum magadiite

Yunfei Bi, Juliette Blanchard, Jean-François Lambert, Yannick Millot, Sandra Casale, Shuangqin Zeng, Hong Nie, Dadong Li

The role of the aluminum source on the insertion of Al in the silicate layers during the hydrothermal crystallization of magadiite (NaSi7O13(OH),4H2O), a lamellar silicate, was investigated. Three aluminum sources were compared: aluminum isopropoxide, aluminum sulfate and aluminum hydroxide We…

Applied Clay Science, 2012, 57, pp.71-78. ⟨10.1016/j.clay.2012.01.005⟩. ⟨hal-00690843⟩

  • Article dans une revue

Antibacterial surfaces developed from bio-inspired approaches

K. Glinel, P. Thébault, Vincent Humblot, Claire-Marie Pradier, T. Jouenne

Prevention of bacterial adhesion and biofilm formation on the surfaces of materials is a topic of major medical and societal importance. Various synthetic approaches based on immobilization or release of bactericidal substances such as metal derivatives, polyammonium salts and antibiotics were…

Acta Biomaterialia, 2012, 8, pp.1670-1684. ⟨10.1016/j.actbio.2012.01.011⟩. ⟨hal-00689996⟩

  • Article dans une revue

Polyol-Made Luminescent and Superparamagnetic β-NaY0.8Eu0.2F4@γ-Fe2O3 Core-Satellites Nanoparticles for Dual Magnetic Resonance and Optical Imaging

Lotfi Ben Tahar, Darine Abi Haidar, Michel Boissiere, Walid Mnasri, Lotfi Ben Tahar, Patricia Beaunier, Michel Boissière, Olivier Sandre, Souad Ammar

Red luminescent and superparamagnetic β-NaY0.8Eu0.2F4@γ-Fe2O3 nanoparticles, made of a 70 nm-sized β-NaY0.8Eu0.2F4 single crystal core decorated by a 10 nm-thick polycrystalline and discontinuous γ-Fe2O3 shell, have been synthesized by the polyol process. Functionalized with citrate ligands they…

Nanomaterials, 2020, 10 (2), pp.393. ⟨10.3390/nano10020393⟩. ⟨hal-02490053v2⟩

  • Article dans une revue

Gold Nanoparticles on Oxide-Free Silicon-Molecule Interface for Single Electron Transport

Louis Caillard, Oliver Seitz, Philip M. Campbell, Rachel P. Doherty, Anne-Félicie Lamic-Humblot, Emmanuelle Lacaze, Yves J. Chabal, Olivier Pluchery

Two different organic monolayers were prepared on silicon Si(111) and modified for attaching gold nanoparticles. The molecules are covalently bound to silicon and form very ordered monolayers sometimes improperly called self-assembled monolayers (SAM). They are designed to be electrically…

Langmuir, 2013, 29, pp.5066-5073. ⟨10.1021/la304971v‎⟩. ⟨hal-00910966⟩

  • Article dans une revue

Hydrodesulfurization of 4,6-Dimethyldibenzothiophene and the Diesel Oil Fraction on NiMo Catalysts Supported over Proton-Exchanged AlMCM-41 and TiMCM-41 Extrudates

Karolina Jaroszewska, Marek Lewandowski, Kinga Góra-Marek, Jolanta Grzechowiak, Gérald Djéga-Mariadassou

NiMo catalysts supported on mesoporous MCM-41 type materials shaped with binder were tested for activity in the hydrodesulfurization of 4,6-dimethyldibenzothiophene (4,6-DMDBT) and the diesel fuel fraction (0.92 wt% of sulfur). The aim of the investigation was to evaluate the effect of ion exchange…

Catalysts, 2021, 11 (9), pp.1086. ⟨10.3390/catal11091086⟩. ⟨hal-03371081⟩

  • Article dans une revue

Controlling the Nanocontact Nature and the Mechanical Properties of a Silica Nanoparticle Assembly

J. Avice, C. Boscher, G. Vaudel, G. Brotons, V. Juvé, M. Edely, C. Methivier, Vitali Goussev, P. Belleville, H. Piombini, P. Ruello

Elaborating advanced nanomaterials based on the assembly of nanoparticles (NPs) is a versatile route for targeting and tuning a wide variety of properties like optical, magnetic, and electrical properties or sensing. This route usually employs a so-called soft chemistry which has the advantage of…

Journal of Physical Chemistry C, 2017, 121 (42), pp.23769-23776. ⟨10.1021/acs.jpcc.7b08404⟩. ⟨hal-02536813⟩