• Article dans une revue

Vanadium-Substituted Phosphomolybdic Acids for the Aerobic Cleavage of Lignin Models-Mechanistic Aspect and Extension to Lignin

Louay Al-Hussaini, Franck Launay, Elena Galvez

This work deals with the aerobic oxidative cleavage of CC and CO bonds catalyzed by the Keggin-type phosphovanadomolybdic acid (H 6 [PMo 9 V 3 O 40 ], noted H 6 PV 3). The latter was synthesized by an adapted hydrothermal procedure classically used for lower vanadium content and was tested as a…

Materials, 2020, 13 (4), pp.812. ⟨10.3390/ma13040812⟩. ⟨hal-02553354⟩

• Communication dans un congrès

CO2 methanation over NiMgAl mixed oxides: Improving their activity via an ultrasound-assisted method

Michel Obeid, Christophe Poupin, Madona Labaki, Samer Aouad, François Delattre, Eric M. Gaigneaux, Josefine Schnee, Edmond Abi-Aad

ICCDU 2023 - 20th International Conference on Carbon Dioxide Utilization, Jun 2023, Bari (IT), Italy. ⟨hal-04346547⟩

• Article dans une revue

Hybrid Hydrophobin/Gold Nanoparticles: Synthesis and Characterization of New Synthetic Probes for Biological Applications

Jane Politi, Luca de Stefano, Paola Giardina, Sandra Casale, Ilaria Rea, Jolanda Spadavecchia

Sensors, 2018, Lecture Notes in Electrical Engineering, 431, pp.169-176. ⟨10.1007/978-3-319-55077-0_23⟩. ⟨hal-03984209⟩

• Article dans une revue

Flavonols and 3-hydroxychromones: new applications for a class of environment-sensitive fluorescent molecules

Stefano Protti, Alberto Mezzetti

Flavonols are naturally-occuring molecules that exhibit interesting fluorescence properties. Thanks to an excited-state intramolecular proton transfer, to specific interactions with their molecular environment and to ground-state proton transfer reactions, very often a dual or even triple…

Chimica Oggi - Chemistry Today, 2020, 38, pp.34-37. ⟨hal-04025211⟩

• Article dans une revue

Preparation, characterization, and hydrogenation activity of new Rh 0 –MCM-41 catalysts prepared from as-synthesized MCM-41 and RhCl 3

Maya Boutros, Georges Moarbess, Thomas Onfroy, Franck Launay

Impregnation of as-synthesized MCM-41 silica by ethanolic solutions of rhodium(III) chloride was tested as an alternative to its introduction into the synthesis gel to get, after calcination and reduction by H2, highly dispersed metal(0) nanoparticles throughout the mesopores network. Rh(III) and…

Comptes Rendus. Chimie, 2018, 21 (5), pp.514-522. ⟨10.1016/j.crci.2018.01.003⟩. ⟨hal-04020427⟩

• Article dans une revue

Solvent effects on the vibrational spectrum of 3-hydroxyflavone

Ari Paavo Seitsonen, Abdenacer Idrissi, Stefano Protti, Alberto Mezzetti

3-hydroxyflavone (3HF) is a widely studied molecule that acts as a simplified prototype of biological, more complex flavonoids. Its solvation mechanism is still under investigation. Here we report a joint experimental and simulation study of the vibrational properties of 3HF in gas phase and in…

Journal of Molecular Liquids, 2019, 275, pp.723-728. ⟨10.1016/j.molliq.2018.11.020⟩. ⟨cea-04075728⟩

• Article dans une revue

Metal-free platforms for molecular thin films as high-performance supercapacitors

Ritu Gupta, Ankur Malik, Kusum Kumari, Saurabh Kumar Singh, Vincent Vivier, Prakash Chandra Mondal

Oligomeric thin films of anthracene, pyrene, and naphthalene are electrochemically prepared on graphite rods for understanding enhanced supercapacitor explained through proton-coupled electron-transfer and electrical double-layer mechanism.

Chemical Science, 2024, 15 (23), pp.8775-8785. ⟨10.1039/D4SC00611A⟩. ⟨hal-04775537⟩

• Article dans une revue

Cu segregation in Au–Cu nanoparticles exposed to hydrogen atmospheric pressure: how is fcc symmetry maintained?

Q. Wang, A. Nassereddine, D. Loffreda, C. Ricolleau, D. Alloyeau, C. Louis, L. Delannoy, J. Nelayah, H. Guesmi

In a recent work [A. Nassereddine et al., Small 2021, 17, 2104571] we reported the atomic-scale structure and dynamics of sub-4 nm sized Au nanoparticles (NPs) supported on titania in H2 at atmospheric pressure obtained by using aberration-corrected environmental transmission electron microscopy (…

Faraday Discussions, 2022, 242, pp.375-388. ⟨10.1039/D2FD00130F⟩. ⟨hal-03863753v2⟩

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Unlocking synergy in bimetallic catalysts by core–shell design

Jessi van der Hoeven, Jelena Jelic, Liselotte Olthof, Giorgio Totarella, Relinde van Dijk-Moes, Jean-Marc Krafft, Catherine Louis, Felix Studt, Alfons van Blaaderen, Petra de Jongh

Extending the toolbox from mono- to bimetallic catalysts is key in realizing efficient chemical processes1. Traditionally, the performance of bimetallic catalysts featuring one active and one selective metal is optimized by varying the metal composition1,2,3, often resulting in a compromise between…

Nature Materials, 2021, 20 (9), pp.1216-1220. ⟨10.1038/s41563-021-00996-3⟩. ⟨hal-03995585⟩

• Article dans une revue

Laccase production from sucrose by recombinant Yarrowia lipolytica and its application to decolorization of environmental pollutant dyes

Farshad Darvishi, Marzieh Moradi, Claude Jolivalt, Catherine Madzak

Laccases are used in decolorization and biodegradation of synthetic dyes, bioremediation of industrial waste-waters and delignification of lignocellulosic compounds. The aims of the present study were the optimization of a recombinant laccase production in Yarrowia lipolytica yeast using sucrose as…

Ecotoxicology and Environmental Safety, 2018, 165, pp.278-283. ⟨10.1016/j.ecoenv.2018.09.026⟩. ⟨hal-02621256⟩