• Article dans une revue

Selective hydrodechlorination of 1,2-dichloroethane on NiSiBEA zeolite catalyst: Influence of the preparation procedure on a high dispersion of Ni centers

R. Baran, I.I. Kamińska, A. Śrębowata, S. Dzwigaj

NixSiBEA zeolites (x = 1-2 Ni wt.%) were prepared by a two-steps postsynthesis method which consists of (1) creation of vacant T-sites by dealumination of tetraethylammonium BEA zeolite with nitric acid and then (2) impregnation of resulting SiBEA zeolite with an aqueous solution of Ni(NO3)2,…

Microporous and Mesoporous Materials, 2013, 169, pp.120-127. ⟨10.1016/j.micromeso.2012.11.005⟩. ⟨hal-00811551⟩

• Article dans une revue

Role of oxygen vacancies in the basicity of ZnO: From the model methylbutynol conversion to the ethanol transformation application

C. Drouilly, J.M. Krafft, F. Averseng, H. Lauron-Pernot, Delphine Bazer-Bachi, Céline Chizallet, V. Lecocq, Guylène Costentin

The parameters governing the basic reactivity of kadox and ex-carbonate zinc oxide samples towards alcohol conversion were investigated varying the atmosphere of pre-treatment for a model reaction, the methylbutynol (MBOH) conversion, and the ethanol conversion reaction, a transformation of…

Applied Catalysis A : General, 2012, 453, pp.121-129. ⟨10.1016/j.apcata.2012.11.045⟩. ⟨hal-00811509⟩

• Article dans une revue

Low temperature dry methane reforming over Ce, Zr and CeZr promoted Ni–Mg–Al hydrotalcite-derived catalysts

Radosław Dębek, Maria Elena Galvez, Franck Launay, Monika Motak, Teresa Grzybek, Patrick da Costa

Hydrotalcite derived catalysts promoted with Ce, Zr and CeZr showed considerable activity in dry methane reforming (DMR) at low temperatures (550°C). Direct methane decomposition resulting in the extensive formation of fishbone-type carbon nanofibers was substantially inhibited in the presence of…

International Journal of Hydrogen Energy, 2016, 41 (27), pp.11616-11623. ⟨10.1016/j.ijhydene.2016.02.074⟩. ⟨hal-01289149⟩

• Article dans une revue

The controlled synthesis of metal-acid bifunctional catalysts: Selective Pt deposition and nanoparticle synthesis on amorphous aluminosilicates

Jadid E. Samad, Juliette Blanchard, Celine Sayag, Catherine Louis, John R. Regalbuto

The rational synthesis of metal-acid bifunctional catalysts based on aluminosilicates will involve control over which domain – alumina or silica – the metal can be deposited on, as well as the control of particle size. These factors determine the ratio and proximity of the metal and acid sites. The…

Journal of Catalysis, 2016, 342, pp.213 - 225. ⟨10.1016/j.jcat.2016.08.002⟩. ⟨hal-01564217⟩

• Poster de conférence

Direct insight into the activation mechanism of Fe and Sb catalysts by operando TEM and XAS techniques

Aliou Sadia Traore, Walid Baaziz, Yong Zhou, Andrei Khodakov, Mirella Virginie, E. Marceau, Vitaly Ordomsky, Sharmin Sharna, Valérie Briois, Ovidiu Ersen

Operando VII, May 2023, Grindelwald, Switzerland. ⟨hal-04523746⟩

• Article dans une revue

Modelling of a Lean NOx-Trap system with NO/NO2 differentiation and sulfur poisoning

Alexis Manigrasso, Pierre Darcy, Patrick da Costa

One of the challenges in the automotive industry is to develop new vehicles and new technologies with minimal costs. In this context, modeling becomes an important tool for the design of future technologies by reducing the number of tests needed to develop a new exhaust system. With the emergence…

SAE International Journal of Fuels and Lubricants, 2010, 3 (2), pp.414-424. ⟨hal-00604776⟩

• Chapitre d'ouvrage

Mechanisms of Adsorption of Short Peptides on Metal and Oxide Surfaces

Vincent Humblot, Jessem Landoulsi, Claire-Marie Pradier

Biointerfaces, involving peptides or proteins and solid surfaces, have been investigated with the aim of controlling the behavior/reactivity of inorganic materials in biological environments. This chapter presents a comprehensive overview of the basic aspects governing the interaction of short…

Peptide Materials: From Nanostructures to Applications, Wiley Online Library, pp.289-312, 2013, ⟨10.1002/9781118592403.ch11⟩. ⟨hal-00958136⟩

• Article dans une revue

Enhancing low-temperature activity and durability of Pd-based diesel oxidation catalysts using ZrO2 supports

Mi-Young Kim, Eleni A. Kyriakidou, Jae-Soon Choi, Todd J. Toops, Andrew J. Binder, Cyril Thomas, James E. Parks, Viviane Schwartz, Jihua Chen, Dale K. Hensley

We investigated the impact of ZrO2 on the performance of palladium-based oxidation catalysts with respect to low-temperature activity, hydrothermal stability, and sulfur tolerance. Pd supported on ZrO2 and SiO2 were synthesized for a comparative study. Additionally, in an attempt to maximize the…

Applied Catalysis B: Environmental, 2016, 187, pp.181-194. ⟨10.1016/j.apcatb.2016.01.023⟩. ⟨hal-01264140⟩

• Article dans une revue

Aqueous-Phase Preparation of Model HDS Catalysts on Planar Alumina Substrates: Support Effect on Mo Adsorption and Sulfidation

Cédric Bara, Lucie Plais, Kim Larmier, Elodie Devers, Mathieu Digne, Anne-Félicie Lamic-Humblot, Gerhard D. Pirngruber, Xavier Carrier

The role of the oxide support on the structure of the MoS2 active phase (size, morphology, orientation, sulfidation ratio, etc.) remains an open question in hydrotreating catalysis and biomass processing with important industrial implications for the design of improved catalytic formulations. The…

Journal of the American Chemical Society, 2015, 137 (50), pp.15915-15928. ⟨10.1021/jacs.5b10975⟩. ⟨hal-01263787⟩

• Article dans une revue

Electron Transfer at the Metal Oxide/Electrolyte Interface: A Simple Methodology for Quantitative Kinetics Evaluation

Iban Azcarate, Cyrille Costentin, Christophe Méthivier, Christel Laberty-Robert, Alexis Grimaud

While quantitative models exist for measuring rate constants for electron exchange at the surface of semiconductors to or from redox couples in solution, their use is very limited for studying transition metal oxide electrodes. Taking advantage of the possibility of tuning the doping level of WO 3…

Journal of Physical Chemistry C, 2018, 122 (24), pp.12761-12770. ⟨10.1021/acs.jpcc.8b02289⟩. ⟨hal-02388362⟩