• Article dans une revue

Effect of ceria promotion on the catalytic performance of Ni/SBA-16 catalysts for CO 2 methanation

Chao Sun, Patricia Beaunier, Patrick da Costa

The presence of Ce inside the SBA-16 structure promoted the ratio of Ce 3+ and medium basic sites and thus favoured CH 4 formation.

Catalysis Science & Technology, 2020, 10 (18), pp.6330-6341. ⟨10.1039/D0CY00922A⟩. ⟨hal-04025210⟩

• Article dans une revue

Au-Modified Pd catalyst exhibits improved activity and stability for NO direct decomposition

Taha Elgayyar, Josefine Schnee, Alain Tuel, Laurence Burel, Francoise Bosselet, Yves Schuurman, Frederic C Meunier, Laurent Delannoy, Cyril Thomas

The direct decomposition of NO x at moderate temperatures is a challenge because of the poisoning of the surface of noble metals by oxygen, yet the modification of Pd with Au enables obtaining a highly stable catalyst under an O 2-free feed at 450°C. Care was taken to ensure that the reaction was…

Catalysis Science & Technology, 2021, 11, pp.2908 - 2914. ⟨10.1039/d1cy00301a⟩. ⟨hal-03240877⟩

• Communication dans un congrès

On the graphical analysis of the impedance response of passive electrodes

Mai T.T. Tran, Oumaïma Gharbi, Mark E Orazem, Bernard Tribollet, Mireille Turmine, Vincent Vivier

The analysis of the capacitive behavior of a passive electrode is often a difficult subject because the response obtained by electrochemical impedance spectroscopy (EIS) is characterized by a non-ideal behavior that we try to model by using a constant phase element (CPE) [1, 2]. In doing so, both…

241st ECS Meeting of The Electrochemical Society, ECS, May 2022, Vancouver (CA), Canada. ⟨hal-03994070⟩

• Article dans une revue

Potent antimicrobial peptides against Legionella pneumophila and its environmental host, Acanthamoeba castellanii.

Margot Schlusselhuber, Vincent Humblot, Sandra Casale, Christophe Méthivier, Julien Verdon, Matthias Leippe, Jean-Marc Berjeaud

Legionella pneumophila, the major causative agent of Legionnaires' disease, is most often found in the environment in close association with free-living amoebae, leading to persistence, spread, biocide resistance, and elevated virulence of the bacterium. In the present study, we evaluated the…

Applied Microbiology and Biotechnology, 2015, 99 (11), pp.4879-91. ⟨10.1007/s00253-015-6381-z⟩. ⟨hal-01427428⟩

• Article dans une revue

Exploring the self-assembly of dumbbell-shaped polyoxometalate hybrids, from molecular building units to nanostructured soft materials

Mireia Segado Centellas, Madeleine Piot, Raphaël Salles, Anna Proust, Ludovic Tortech, Dalil Brouri, Sébastien Hupin, Benjamin Abécassis, David Landy, Carles Bo, Guillaume Izzet

The formation of hierarchical nanostructures using preformed dumbbell-like species made of covalent organic–inorganic polyoxometalate (POM)-based hybrids is herein described. In this system, the presence of charged subunits (POM, metal linkers, and counter ions) in the complex molecular…

Chemical Science, 2020, 11 (40), pp.11072 - 11080. ⟨10.1039/D0SC03243C⟩. ⟨hal-02954983⟩

• Article dans une revue

Unraveling the Direct Decomposition of NO x over Keggin Heteropolyacids and Their Deactivation Using a Combination of Gas-IR/MS and In Situ DRIFT Spectroscopy

Josefine Schnee, Laurent Delannoy, Guylène Costentin, Cyril Thomas

Keggin heteropolyacids (HPAs) have been known to be efficient NOx absorbers for many years, and to decompose a significant fraction of the NOx species pre-absorbed at 100-150 °C into harmless N2 and O2 upon rapid heating to 450 °C. However, this capability of Keggin HPAs to directly decompose NOx…

Journal of Physical Chemistry C, In press, ⟨10.1021/acs.jpcc.0c05945⟩. ⟨hal-02960399⟩

• Article dans une revue

Stability of Binary SAMs Formed by omega-Acid and Alcohol Functionalized Thiol Mixtures

Frederik Tielens, Vincent Humblot, Claire-Marie Pradier, Monica Calatayud, Francesc Illas

A simple model is presented to describe the mixing process of acid- and alcohol-terminated thiol self-assembled monolayers (SAMs) on Au(111). It was found that the low-concentration acid-terminated SAMs are enriched in acid thiol compared with the original solution from which the SAM is made. Due…

Langmuir, 2009, 25 (17), pp.9980-9985. ⟨10.1021/la901127g⟩. ⟨hal-01361365⟩

• Article dans une revue

Design of TiO2/Au nanoparticle films with controlled crack formation and different architectures using a centrifugal strategy

Abdelhafed Taleb, Frederic Mesguich, Thomas Onfroy, Xue Yanpeng

Here we present an approach to design hybrid nanocomposite films based on TiO2/Au nanoparticles using centrifugation processes. The prepared nanocomposite films have been characterized by different techniques such as FEGSEM, TEM, BET and XRD. Furthermore it is demonstrated that centrifugal force…

RSC Advances, 2015, 5 (10), pp.7007-7017. ⟨10.1039/C4RA13829E⟩. ⟨hal-01121614⟩

• Communication dans un congrès

Electron transfer dynamics in guest/host materials

A. Legrand, A. Moissette, M. Hureau, H. Vezin, P. Massiani

Marie Sklodowska-Curie symposium on the Foundations of Physical Chemistry, Nov 2011, Varsovie, Poland. ⟨hal-00642027⟩

• Article dans une revue

Melanin Polymerization Held in Check: A Composite of Dihydroxyphenylalanine with Zeolite Beta

Meryem Bouchoucha, Frederik Tielens, Fabrice Gaslain, France Costatorro, Sandra Casale, Ana Palcic, Valentin Valtchev, Jean-François Lambert, Maguy Jaber

Journal of Physical Chemistry C, 2015, 119 (16), pp.8736-8747. ⟨10.1021/acs.jpcc.5b01194⟩. ⟨hal-02403166⟩