• Article dans une revue

Hierarchical Self-Assembly of Polyoxometalate-Based Hybrids Driven by Metal Coordination and Electrostatic Interactions: From Discrete Supramolecular Species to Dense Monodisperse Nanoparticles

Guillaume Izzet, Benjamin Abécassis, Dalil Brouri, Madeleine Piot, Benjamin Matt, Stefano Artin Serapian, Carles Bo, Anna Proust

The metal-driven self-assembly processes of a covalent polyoxometalate (POM)-based hybrid bearing remote terpyridine binding sites have been investigated. In a strongly dissociating solvent, a discrete metallomacrocycle, described as a molecular triangle, is formed and characterized by 2D diffusion…

Journal of the American Chemical Society, 2016, 138 (15), pp.5093 - 5099. ⟨10.1021/jacs.6b00972⟩. ⟨hal-01548125⟩

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Zn-Cu Alloy Nanofoams as Efficient Catalysts for the Reduction of CO 2 to Syngas Mixtures with a Potential-Independent H 2 /CO Ratio

Sarah Lamaison, David Wakerley, David Montero, Gwenaëlle Rousse, Dario Taverna, Domitille Giaume, Dimitri Mercier, Juliette Blanchard, Huan Ngoc Tran, Marc Fontecave, Marc Mougel

Alloying strategies are commonly used to design electrocatalysts that take on properties of their constituent elements. Herein, we explore the use of such a strategy to develop Zn-Cu alloyed electrodes with unique hierarchical porosity and tunable selectivity for CO2 vs. H + reduction. By varying…

ChemSusChem, 2019, 12 (2), pp.511-517. ⟨10.1002/cssc.201802287⟩. ⟨hal-02182388⟩

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Cyanobacterial formation of intracellular Ca-carbonates in undersaturated solutions

Nithavong Cam, Karim Benzerara, Thomas Georgelin, Maguy Jaber, Jean-François Lambert, Mélanie Poinsot, Fériel Skouri-Panet, David Moreira, Purificacion Lopez-Garcia, Emmanuelle Raimbault, Laure Cordier, Didier Jezequel

Geobiology, 2018, 16 (1), pp.49-61. ⟨10.1111/gbi.12261⟩. ⟨hal-01655173⟩

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Successive Strong Electrostatic Adsorptions of [RhCl6]3– on Tungstated-Ceria as an Original Approach to Preserve Rh Clusters From Sintering Under High-Temperature Reduction

Jeffrey Miller, Neil Schweitzer, Mimoun Aouine, Philippe Vernoux, Abdelmalik Boufar, Juliette Blanchard, Jean-Marc Krafft, Christophe Méthivier, Céline Sayag, Frédéric Ser, Mickaël Sicard, Cyril Thomas

Supported transition metal materials have been identified as ideal candidates for decades to catalyze various reactions of interest in the fields of hydrocarbon refining, energy and environmental catalysis. As the resources in transition metals on earth are known to be limited, it appears to be of…

Journal of Physical Chemistry C, 2021, 125 (45), pp.25094-25111. ⟨10.1021/acs.jpcc.1c07644⟩. ⟨hal-03449235⟩

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Cyto- and bio-compatibility assessment of plasma-treated polyvinylidene fluoride scaffolds for cardiac tissue engineering

Maria Kitsara, Gaëlle Revet, Jean-Sébastien Vartanian-Grimaldi, Alexandre Simon, Mathilde Minguy, Antoine Miche, Vincent Humblot, Thierry Dufour, Onnik Agbulut

As part of applications dealing with cardiovascular tissue engineering, drop-cast polyvinylidene fluoride (PVDF) scaffolds have been treated by cold plasma to enhance their adherence to cardiac cells. The scaffolds were treated in a dielectric barrier device where cold plasma was generated in a…

Frontiers in Bioengineering and Biotechnology, 2022, 10, pp.1008436. ⟨10.3389/fbioe.2022.1008436⟩. ⟨hal-03889499v2⟩

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The structural and the photoelectrochemical properties of ZnO–ZnS/ITO 1D hetero-junctions prepared by tandem electrodeposition and surface sulfidation: on the material processing limits

A. Brayek, S. Chaguetmi, M. Ghoul, I. Ben Assaker, R. Chtourou, P. Decorse, P. Beaunier, S. Nowak, F. Mammeri, S. Ammar

ZnO–ZnS 1D hetero-nanostructures were prepared by an easy and scalable processing route. It consists of ZnO nanorod electrodeposition on ITO substrate and surface sulfidation by ion exchange in an aqueous Na 2 S solution. Increasing the treatment contact time (t c) from 8 to 48 h involves different…

RSC Advances, 2018, 8 (21), pp.11785 - 11798. ⟨10.1039/c8ra00176f⟩. ⟨hal-01748875⟩

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Mesocellular silica foam-based Ni catalysts for dry reforming of CH4 (by CO2)

Oscar Daoura, Marie-Nour Kaydouh, Nissrine El-Hassan, Pascale Massiani, Franck Launay, Maya Boutros

Journal of CO2 Utilization, 2018, 24, pp.112-119. ⟨10.1016/j.jcou.2017.12.010⟩. ⟨hal-02414803⟩

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Influence of the ultrasound power density in the ultrasound-assisted synthesis of Ni-based LDH catalysts for CO2 methanation

Michel Obeid, Christophe Poupin, Madona Labaki, Sharad Gupta, Samer Aouad, François Delattre, Ferdaous Ben Romdhane, François Devred, Eric Gaigneaux, Josefine Schnee, Edmond Abi-Aad

Journal of Environmental Chemical Engineering, 2024, 12 (5), pp.Id 114059. ⟨10.1016/j.jece.2024.114059⟩. ⟨hal-04709955⟩

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Stabilisation of small mono- and bimetallic gold–silver nanoparticles using calix[8]arene derivatives

Priyanka Ray, Marie Clément, Cyril Martini, Ibrahim Abdellah, Patricia Beaunier, José-Luis Rodriguez-Lopez, Vincent Huc, Hynd Remita, Isabelle Lampre

New Journal of Chemistry, 2018, 42 (17), pp.14128-14137. ⟨10.1039/C8NJ02451K⟩. ⟨hal-02399078⟩

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High pressures pathway toward boron-based nanostructured solids

Remi Grosjean, Yann Le Godec, Simon Delacroix, Guillaume Gouget, Patricia Beaunier, Ovidiu Ersen, Dris Ihiawakrim, Oleksandr O Kurakevych, Corinne Chanéac, David Portehault

Inorganic nanocomposites made of an inorganic matrix containing nanoparticle inclusions provide materials of advanced mechanical, magnetic, electrical properties and multifunctionality. The range of compounds that can be implemented in nanocomposites is still narrow and new preparation methods are…

Dalton Transactions, 2018, 47 (23), pp.7634-7639. ⟨10.1039/C8DT00932E⟩. ⟨hal-01883827⟩