Laboratoire de réactivité de surface

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  • Article dans une revue

Total oxidation of propene over Au/xCeO(2)-Al2O3 catalysts: Influence of the CeO2 loading and the activation treatment

Pandian Lakshmanan, Laurent Delannoy, Vincent Richard, Christophe Methivier, Claude Potvin, Catherine Louis

This study explores the reaction of oxidation of propene (1200 ppm) under excess oxygen (9%) over Au/xCeO(2)/Al2O3 catalysts (x = 1.5, 3, 5, and 10 wt% CeO2) to mimic the conditions of VOC decomposition. The present study reveals the influence of several factors that affect the oxidative…

Applied Catalysis B: Environmental, 2010, 96 (1-2), pp.117-125. ⟨10.1016/j.apcatb.2010.02.009⟩. ⟨hal-00604727⟩

  • Article dans une revue

Optimized immobilization of gold nanoparticles on planar surfaces through alkyldithiols and their use to build 3D biosensors

Anne-Laure Morel, Rose-Marie Volmant, Christophe Methivier, Jean-Marc Krafft, Souhir Boujday, Claire-Marie Pradier

This paper describes a controlled way to immobilize gold nanoparticles on planar gold surfaces and the use of the resulting 3D platform to build up a 3D biosensor. The surface was first functionalized by grafting hexanedithiol, this molecule has 2 thiol end groups, which enables its chemical…

Colloids and Surfaces B: Biointerfaces, 2010, 81 (1), pp.304-312. ⟨10.1016/j.colsurfb.2010.07.021⟩. ⟨hal-00604782⟩

  • Article dans une revue

N-Methylephedrium Salts as Chiral Surfactants for Asymmetric Hydrogenation in Neat Water with Rhodium(0) Nanocatalysts

Elodie Guyonnet Bile, Audrey Denicourt-Nowicki, Rita Sassine, Patricia Beaunier, Franck Launay, Alain Roucoux

Synthesis of a water-sol. family of optically active N-methylephedrium salts NMeEph12X I [X = Br, HCO3, (S)-lactate] that can be used as efficient protective agents of metallic nanoparticles in neat water was described. The resulting materials were evaluated in the asym. hydrogenation of…

ChemSusChem, 2010, 3 (11), pp.1276-1279. ⟨10.1002/cssc.201000206⟩. ⟨hal-00604720⟩

  • Article dans une revue

Origins of the deactivation process in the conversion of methylbutynol on zinc oxide monitored by operando DRIFTS

C. Drouilly, J.M. Krafft, F. Averseng, H. Lauron-Pernot, Delphine Bazer-Bachi, Céline Chizallet, V. Lecocq, G. Costentin

conversion reaction. The formation of acetone and acetylene is indicative of the basic properties of the zinc oxide surface. This basic catalyst, whose conversion level depends on the nature of the pre-treatment, was found to deactivate versus time on stream. Poisoning the basic sites by CO2 pre-…

Catalysis Today, 2012, 205, pp.67-75. ⟨10.1016/j.cattod.2012.08.011⟩. ⟨hal-00809404⟩

  • Article dans une revue

A simple thermodynamic approach to predict responses from polymer-coated quartz crystal microbalance sensors exposed to organic vapors.

P. Palmas, J. Klingenfus, A. Vedeau, E. Girard, P. Montméat, L. Hairault, C.M. Pradier, C. Methivier

As of lately, the demand for developing artificial sensors with improved capabilities for the detection of explosives, toxics or drugs has increased. Ideally, sensor devices should provide high sensitivity and give a response that is specific to a given target molecule without being influenced by…

Talanta, 2013, 115, pp.616-623. ⟨10.1016/j.talanta.2013.06.017⟩. ⟨hal-00958092⟩

  • Article dans une revue

Interaction of ZnII porphyrin with TiO2 nanoparticles: from mechanism to synthesis of hybrid nanomaterials.

Jolanda Spadavecchia, Christophe Méthivier, Jessem Landoulsi, Claire-Marie Pradier

The mechanism of interaction of Zn porphyrin (ZnPP) with TiO2 surfaces is investigated with a view to optimizing the synthesis of hybrid nanomaterials. The strategy consists of studying the adsorption of ZnPP on TiO2 flat surfaces by taking advantage of complementary surface characterization…

ChemPhysChem, 2013, 14, pp.2462-2469. ⟨10.1002/cphc.201300193⟩. ⟨hal-00983739⟩

  • Article dans une revue

Improved activity and stability in CO oxidation of bimetallic Au-Cu/TiO2 catalysts prepared by deposition-precipitation with urea

A. Sandoval, Catherine Louis, Rodolfo Zanello

Au-Cu bimetallic catalysts supported on TiO2 were prepared for the first time by sequential deposition-precipitation with the urea method, copper first then gold. Au-Cu catalysts with four different Au:Cu atomic ratios were synthesized (1:0.4 to 1:1.2). This method allowed quantitative deposition…

Applied Catalysis B: Environmental, 2013, 140-141, pp.363-377. ⟨10.1016/j.apcatb.2013.04.039⟩. ⟨hal-00911705⟩

  • Article dans une revue

On the origin of the optimum loading of Ag on Al2O3 in the C3H6-SCR of NOx

Tesnim Chaieb, Laurent Delannoy, Catherine Louis, Cyril Thomas

Ag/Al2O3 catalysts synthesized by the common impregnation technique with various Ag loadings were characterized by the NOx-Temperature-Programmed Desorption (TPD) method and their catalytic performances were evaluated in the selective catalytic reduction of NOx by propene (C3H6-SCR). It was found…

Applied Catalysis B: Environmental, 2013, 142-143, pp.780-784. ⟨10.1016/j.apcatb.2013.06.010⟩. ⟨hal-00907584⟩

  • Article dans une revue

Room-Temperature Synthesis of Iron-Doped Anatase TiO2 for Lithium-Ion Batteries and Photocatalysis

Christian Andriamiadamanana, C. Laberty-Robert, Moulay Tahar Sougrati, Sandra Casale, Carine Davoisne, Snehangshu Patra, Frédéric Sauvage

Iron-doped nanocrystalline particles of anatase TiO2 have been successfully synthesized using a complete room-temperature synthetic approach, leading to particles of high surface area (280 m2/g) and a narrowed band gap of 2.3 eV. These particles were introduced for photocatalysis under white light…

Inorganic Chemistry, 2014, pp.10129-10139. ⟨10.1021/ic501067p⟩. ⟨hal-01094375⟩

  • Article dans une revue

Gold/Polyoxometalate Core/Shell Nanoparticles for Combined Chemotherapy–Photothermal Cancer Therapy

Somia Tomane, Claire Wilhelm, Souhir Boujday, Alexandre Fromain, Antoine Miche, Flavien Bourdreux, Anne Dolbecq, Pierre Mialane, Anne Vallée

We designed monodisperse and perfectly shaped core/shell AuNP@Mo4Zol2Mn nanohybrids consisting of gold nanoparticles (AuNPs) functionalized by an antitumoral polyoxometalate (POM) incorporating the biologically active zoledronate ligand. After incubation, the nanoparticles were readily confined in…

ACS Applied Nano Materials, 2021, 4 (3), pp.2339-2344. ⟨10.1021/acsanm.0c03187⟩. ⟨hal-03214106⟩