• Article dans une revue

Quantitative Investigation of MgO Bronsted Basicity: DFT, IR, and Calorimetry Study of Methanol Adsorption

Hugo Petitjean, Konstantin Tarasov, Francoise Delbecq, Philippe Sautet, Jean-Marc Krafft, Philippe Bazin, Maria Cristina Paganini, Elio Giamello, Michel Che, Helene Lauron-Pernot, Guylene Costentin

The adsorption geometries, energies, and vibrational frequencies of methanol on MgO defective surfaces have been calcd. by periodic DFT simulations. The results are very comparable with those obtained with water and are also in very good accordance with microcalorimetry and IR expts. At low…

Journal of Physical Chemistry C, 2010, 114 (7), pp.3008-3016. ⟨10.1021/jp909354p⟩. ⟨hal-00604791⟩

• Chapitre d'ouvrage

Investigation of different preparation methods of PtIr, PtIrSn and PtIrGe catalysts

Christophe Poupin, Camille La Fontaine, Laurence Pirault-Roy

Studies in Surface Science and Catalysis, pp.467-470, 2010, ⟨10.1016/S0167-2991(10)75086-2⟩. ⟨hal-02497268⟩

• Article dans une revue

On the corrosion resistance of the CoCrFeMnNi high entropy alloys in chloride-containing sulfuric acid solutions

Yaojun Hou, Baojie Dou, Chenyang Xie, Fan Sun, Stéphane Rioual, Benoit Lescop, Kevin Ogle, Antoine Miche, Oumaïma Gharbi, Mireille Turmine, Vincent Vivier

The electrochemical reactivity of the high entropy Cantor alloy (CoCrFeMnNi) was investigated via potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS), and surface analysis as a function of chloride content, in sulfuric acid solutions. The results revealed that…

Applied Surface Science, 2024, 681, pp.161487. ⟨10.1016/j.apsusc.2024.161487⟩. ⟨hal-04775546⟩

• Article dans une revue

Mechanism of RuO2 Crystallization in Borosilicate Glass: An Original in Situ ESEM Approach

Hassiba Boucetta, Renaud Podor, Lorenzo Stievano, Johann Ravaux, Xavier Carrier, Sandra Casale, S. Gossé, Amélie Monteiro, Sophie Schuller

Ruthenium, a fission product arising from the reprocessing of spent uranium oxide (UOX) fuel, crystallizes in the form of acicular RuO2 particles in high-level waste containment glass matrices. These particles are responsible for significant modifications in the physicochemical behavior of the…

Inorganic Chemistry, 2012, 51, pp.3478-3489. ⟨10.1021/ic202156y⟩. ⟨hal-00684182⟩

• Article dans une revue

Probing the Binding Mechanism of Peptides on a Copper Surface: Multi layer Self-Assembly Promoted by Glutamate Residues

Christophe Methivier, Victor Lebec, Jessem Landoulsi, Claire-Marie Pradier

Short peptides interact strongly with copper surfaces We report here a full characterization on the Interaction of Gly-Pto and the Cu(110) surface: By combining infrared analysis with X-ray photoelectron spectroscopy, two binding centers have been identified: the carboxylate and the amino groups…

Journal of Physical Chemistry C, 2011, 115 (10), pp.4041-4046. ⟨hal-00602943⟩

• Communication dans un congrès

Preparation of SiO2-supported Ni-Fe nanoparticles exhibiting a Fe gradient for the hydrogenation of sugars in water

Francois Robert, Achraf Sadier, Catherine Amiens, Karine Philippot, Robert Wojcieszak, E. Marceau

13th International Symposium on the Preparation of Heterogeneous Catalysts (PREPA13), Jul 2023, Louvain-la-Neuve, Belgium. ⟨hal-04523325⟩

• Article dans une revue

Anchoring of Pt(II) Pyridyl Complex to Mesoporous Silica Materials: Enhanced Photoluminescence Emission at Room Temperature and Photooxidation Activity using Molecular Oxygen

Kohsuke Mori, Kentaro Watanabe, Masayoshi Kawashima, Michel Che, Hiromi Yamashita

Chloro(2,2':6',2''-terpyridine)platinum(II) ([Pt(tpy)Cl]Cl) complex was successfully anchored to a series of (3-aminopropyl)trimethoxysilane-modified mesoporous silica materials (MCM-41, SBA-15, and MCM-48). Pt LIII-edge x-ray absorption fine structure (XAFS) measurements reveal…

Journal of Physical Chemistry C, 2011, 115 (4), pp.1044-1050. ⟨10.1021/jp105577f⟩. ⟨hal-00602944⟩

• Article dans une revue

Investigation of ion-selective electrodes with neutral ionophores and ionic sites by EIS. I. Theory

Claude Gabrielli, Patrick Hemery, Pierre Letellier, Michele Masure, Hubert Perrot, Marie-Isabelle Rahmi, Mireille Turmine

Models of an ion selective electrode involving an ionophore and mobile sites in a membrane are proposed. The first model, called the phase boundary potential model, supposed thermodynamic equilibrium; it allows the concentrations of the various species to be calculated. Then, a kinetic model, which…

Journal of Electroanalytical Chemistry, 2004, 570 (2), pp.275-289. ⟨10.1016/j.jelechem.2004.04.006⟩. ⟨hal-04197728⟩

• Article dans une revue

Mueller micropolarimeter for color imaging of aluminium metasurfaces

M. Nicolas, I. Soumahoro, L. Zhang, G. Guida, W. Daney de Marcillac, D. Demaille, C. Schwob, S. Boujday, Bruno Gallas

Many anticounterfeiting tags rely on images intricate in different color and/or different polarization states to create optical effects invisible in conventional observation conditions. We build here an imaging micropolarimeter based on the dual rotating compensator system and using the color…

Journal of the Optical Society of America B, 2021, 38 (4), pp.1184. ⟨10.1364/JOSAB.416833⟩. ⟨hal-03178348⟩

• Article dans une revue

Revisiting Alkoxysilane Assembly on Silica Surfaces: Grafting versus Homo-Condensation in Solution

Yannick Millot, Antoine Hervier, Jihed Ayari, Naoures Hmili, Juliette Blanchard, Souhir Boujday

Silica surface functionalization is mandatory for a large variety of applications. This step is often done through the condensation of functional silanes on silanol, silica surfaces' terminal groups. Among these silanes, aminopropyltriethoxysilane (APTES) is widely used due to its assumed high…

Journal of the American Chemical Society, 2023, 145 (12), pp.6671-6681. ⟨10.1021/jacs.2c11390⟩. ⟨hal-04294801⟩