• Article dans une revue

Oxygen reduction reaction monitored during corrosion by means of pumped-micropipette delivery/substrate collection (Pumped-MD/SC) mode of scanning electrochemical microscopy

Abdelilah Asserghine, Sophie Juillard, Julie Ducrot, Vincent Vivier, Carlos Sánchez-Sánchez

The key improvement of the corrosion resistance of metals requires understanding and resolving the electrochemical reactions involved at the local scale. Here, we present the use of the pumped-micropipette delivery/substrate collection (Pumped-MD/SC) mode of scanning electrochemical microscopy (…

Electrochimica Acta, 2023, 441, pp.141775. ⟨10.1016/j.electacta.2022.141775⟩. ⟨hal-03934097⟩

• Article dans une revue

Versatile and robust synthesis process for the fine control of the chemical composition and core-crystallinity of spherical core-shell Au@Ag nanoparticles

Suyeon Lee, Hervé Portalès, Michael Walls, Patricia Beaunier, Nicolas Goubet, Benoit Tremblay, Jérémie Margueritat, Lucien Saviot, Alexa Courty

Au nanoparticles (NPs) characterized by distinct surface chemistry (including dodecanethiol or oleylamine as capping agent), different sizes (~5 and ~10 nm) and crystallinities (polycrystalline or single crystalline), were chosen as seeds to demonstrate the versatility and robustness of our two-…

Nanotechnology, 2021, 32, pp.095604. ⟨10.1088/1361-6528/abc450⟩. ⟨hal-02994816⟩

• Article dans une revue

Elaboration of Prussian Blue Analogue/Silica Nanocomposites: Towards Tailor-Made Nano-Scale Electronic Devices

Giulia Fornasieri, Merwe, Aouadi, Emilie Delahaye, Patricia Beaunier, D. Durand, Eric Rivière, Pierre-Antoine Albouy, François Brisset, Anne Bleuzen

The research of new molecular materials able to replace classical solid materials in electronics has attracted growing attention over the past decade. Among these compounds photoswitchable Prussian blue analogues (PBA) are particularly interesting for the elaboration of new optical memories.…

Materials, 2012, 5, pp.385-403. ⟨10.3390/ma5030385⟩. ⟨hal-00752239⟩

• Article dans une revue

Improved Experimental Setup to Reach a Broad Frequency Domain in Local Electrochemical Impedance Spectroscopy Measurements

Maurilio Pereira Gomes, Samantha Michelle Gateman, Isolda Costa, Oumaïma Gharbi, Kieu Ngo, Jesualdo Luiz Rossi, Mireille Turmine, Vincent Vivier

We report a new experimental setup enabling local electrochemical impedance spectroscopy (LEIS) measurements over a wide frequency range, including the low frequency domain. First, an improved signal treatment was performed using a potential shifter to minimize the DC component of the measured…

Measurement - Journal of the International Measurement Confederation (IMEKO), 2022, 200, pp.111504. ⟨10.1016/j.measurement.2022.111504⟩. ⟨hal-03719357⟩

• Article dans une revue

Microporous polyacrylate matrix containing hydrogen bonded nanotubular assemblies

Farid Ouhib, Emmanuelle Bugnet, Andrei Nossov, Jean-Luc Bonardet, Laurent Bouteiller

We report the straightforward photo-polymn. of polyacrylate films contg. bis-urea based self-assembled nanotubes. The obtained materials are characterized by gas adsorption measurements, 129Xe NMR spectroscopy and WAXS. The presence of the bis-ureas is shown by butane adsorption (at 273 K and…

Polymer, 2010, 51 (15), pp.3360-3364. ⟨10.1016/j.polymer.2010.05.047⟩. ⟨hal-00604788⟩

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In situ observation of atomic redistribution in alloying gold-silver nanorods

Jessi E S van Der Hoeven, Tom a J Welling, Tiago a G da Silva, Jeroen E van den Reijen, Camille La Fontaine, Xavier Carrier, Catherine Louis, Alfons van Blaaderen, Petra E de Jongh

The catalytic performance and optical properties of bimetallic nanoparticles critically depend on the atomic distribution of the two metals in the nanoparticles. However, at elevated temperatures, during light induced heating or during catalysis atomic redistribution can occur. Measuring such metal…

ACS Nano, 2018, 12 (8), pp.8467-8476. ⟨10.1021/acsnano.8b03978⟩. ⟨hal-03157963⟩

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Corrosion and protection of high leaded tin bronze covered with patina in NaHCO3 + Na2SO4 solution simulating acid rain in urban environment

Kamal Rahmouni, Suzanne Joiret, Luc Robbiola, A. Srhiri, Hisasi Takenouti, Vincent Vivier

An experimental procedure for obtaining reproducible patina on high leaded tin bronze, B66 (Cu-8Sn-14Pb in wt %) has been devised, followed by its isolation from the substrate and examination of the electrochemical behaviour in a solution of 0.2 g.L - 1 Na 2 SO 4 + 0.2 g.L - 1 NaHCO 3 acidified to…

Bulgarian Chemical Communications, 2005, 37 (1), pp.26-34. ⟨hal-04189329⟩

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Proton irradiation: a key to the challenge of N-glycosidic bond formation in a prebiotic context

Raffaele Saladino, Bruno M. Bizzarri, Lorenzo Botta, Jiří Šponer, Judit E. Šponer, Thomas Georgelin, Maguy Jaber, Baptiste Rigaud, Michail Kapralov, Gennady N. Timoshenko, Alexei Rozanov, Eugene Krasavin, Anna Maria Timperio, Ernesto Di Mauro

Scientific Reports, 2017, 7 (1), ⟨10.1038/s41598-017-15392-8⟩. ⟨hal-01651973⟩

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Hydrolysis of Ammonia-Borane over Ni/ZIF-8 Nanocatalyst: High Efficiency, Mechanism, and Controlled Hydrogen Release

Changlong Wang, Jimena Tuninetti, Zhao Wang, Chen Zhang, Roberto Ciganda, Lionel Salmon, Sergio Moya, Jaime Ruiz, Didier Astruc

Non-noble metal nanoparticles are notoriously difficult to prepare and stabilize with appropriate,dispersion, which in ttirn severely limits their catalytic functions. Here, using zeolitic imidazolate framework (ZIF-8) as MOF template, catalytically remarkably- efficient, ligand-free first-row late…

Journal of the American Chemical Society, 2017, 139 (33), pp.11610-11615. ⟨10.1021/jacs.7b06859⟩. ⟨hal-01651999⟩

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NO2 disproportionation for the IR characterisation of basic zeolites

Olivier Marie, Nicolas Malicki, Catherine Pommier, Pascale Massiani, Ann Vos, Robert Schoonheydt, Paul Geerlings, Carlos Henriquese, Frédéric Thibault-Starzyk

NO2 disproportionation on alkaline zeolites is used to generate nitrosonium (NO+) and nitrate ions on the surface, and the infrared vibrations observed are very sensitive to the cation chemical hardness and to the basicity of zeolitic oxygen atoms.side pockets of acidic mordenite. We describe here…

Chemical Communications, 2005, pp.1049-1051. ⟨hal-00126967⟩