Laboratoire de réactivité de surface

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  • Article dans une revue

Catalytic hydrogen-assisted dehydrochlorination of 1,2-dichloroethane over cobalt-containing beta zeolite

Anna Śrębowata, Rafal Baran, Izabela I. Kamińska, Thomas Onfroy, Jean-Marc Krafft, Stanislaw Dzwigaj

HAlBEA zeolite obtained by calcination of parent TEABEA zeolite at 823 K for 3 h in air following ion exchange with NH4NO3 solution and calcination at 773 K for 3 h was used for synthesis of cobalt containing zeolite by conventional wet impregnation with an aqueous solution of Co(NO3)2. The…

Catalysis Today, 2015, 251, pp.73-80. ⟨10.1016/j.cattod.2014.10.019⟩. ⟨hal-01226839⟩

  • Article dans une revue

High activity of mononuclear copper present in the framework of CuSiBEA zeolites in the selective catalytic reduction of NO with NH3

Rafal Baran, Teresa Grzybek, Thomas Onfroy, Stanislaw Dzwigaj

CuxSiBEA zeolites (with x = 1–7.5 Cu wt %) prepared by a two-step postsynthesis method which consists in the first step of dealumination of parent BEA zeolite to obtain aluminum-free SiBEA support and then in the second step, of contacting the obtained material with an aqueous solution of copper…

Microporous and Mesoporous Materials, 2016, 226, pp.104-109. ⟨10.1016/j.micromeso.2015.11.065⟩. ⟨hal-01263831⟩

  • Article dans une revue

Prebiotic chemistry

J.F. Lambert, M. Sodupe, P. Ugliengo

Without doubt, one of the most fascinating questions ever asked is ''What is life?'', immediately followed by ''How and where did life arise?''. Both questions are by no means exclusively related to chemistry and biology. Indeed, it was soon realized that…

Chemical Society Reviews, 2012, 41, pp.5373-5374. ⟨10.1039/c2cs90061k⟩. ⟨hal-00809265⟩

  • Article dans une revue

Surface Segregation of Pd from TiO2-Supported AuPd Nanoalloys under CO Oxidation Conditions Observed In situ by ETEM and DRIFTS

Laurent Delannoy, Suzanne Giorgio, Jean-Gabriel Mattei, Claude R. Henry, Nadia El Kolli, Christophe M Éthivier, Catherine Louis

A TiO2-supported AuPd bimetallic catalyst with an Au/Pd atomic ratio of 8 was prepared by deposition-precipitation with urea, and its activity in CO oxidation at room temperature was compared to the one of a monometallic Au/TiO2 catalyst. X-ray photoelectron spectroscopy (XPS) and diffuse…

ChemCatChem, 2013, pp.1-11. ⟨10.1002/cctc.201200618⟩. ⟨hal-00836230⟩

  • Article dans une revue

Origins of the deactivation process in the conversion of methylbutynol on zinc oxide monitored by operando DRIFTS

C. Drouilly, J.M. Krafft, F. Averseng, H. Lauron-Pernot, Delphine Bazer-Bachi, Céline Chizallet, V. Lecocq, G. Costentin

conversion reaction. The formation of acetone and acetylene is indicative of the basic properties of the zinc oxide surface. This basic catalyst, whose conversion level depends on the nature of the pre-treatment, was found to deactivate versus time on stream. Poisoning the basic sites by CO2 pre-…

Catalysis Today, 2012, 205, pp.67-75. ⟨10.1016/j.cattod.2012.08.011⟩. ⟨hal-00809404⟩

  • Article dans une revue

Improved activity and stability in CO oxidation of bimetallic Au-Cu/TiO2 catalysts prepared by deposition-precipitation with urea

A. Sandoval, Catherine Louis, Rodolfo Zanello

Au-Cu bimetallic catalysts supported on TiO2 were prepared for the first time by sequential deposition-precipitation with the urea method, copper first then gold. Au-Cu catalysts with four different Au:Cu atomic ratios were synthesized (1:0.4 to 1:1.2). This method allowed quantitative deposition…

Applied Catalysis B: Environmental, 2013, 140-141, pp.363-377. ⟨10.1016/j.apcatb.2013.04.039⟩. ⟨hal-00911705⟩

  • Article dans une revue

On the origin of the optimum loading of Ag on Al2O3 in the C3H6-SCR of NOx

Tesnim Chaieb, Laurent Delannoy, Catherine Louis, Cyril Thomas

Ag/Al2O3 catalysts synthesized by the common impregnation technique with various Ag loadings were characterized by the NOx-Temperature-Programmed Desorption (TPD) method and their catalytic performances were evaluated in the selective catalytic reduction of NOx by propene (C3H6-SCR). It was found…

Applied Catalysis B: Environmental, 2013, 142-143, pp.780-784. ⟨10.1016/j.apcatb.2013.06.010⟩. ⟨hal-00907584⟩

  • Article dans une revue

Adsorption of functionalised thiols on gold surfaces: how to build a sensitive and selective sensor for a nitroaromatic compound?

F. Thery-Merland, Christophe Méthivier, Eric Pasquinet, Lionel Hairault, Claire-Marie Pradier

Adsorption of thiols of varying structures bearing amine, acid or aromatic functionalities was characterised by Polarisation Modulation Infrared Absorption Spectroscopy (PM-IRRAS). The so functionalised surfaces were then submitted to atmospheres containing traces of 2,4-…

Sensors and Actuators B: Chemical, 2006, 114, pp.223-228. ⟨10.1016/j.snb.2005.04.040⟩. ⟨hal-00111676⟩

  • Article dans une revue

Self-Assembling of Redox-Active Atrazine Poly(ethylenimine) Conjugates – Interfacial Electrochemical and Spectroscopic Characterization

Zhaohui Chen, Michèle Salmain, Claire-Marie Pradier, Nathalie Fischer-Durand, Alain Pailleret, Féthi Bedioui, Sandrine Zanna

Thin films of polymers tethered with both atrazine haptens and ferrocenyl (Fc) probes were formed on polycrystalline gold electrodes by taking advantage of the facile formation of self-assembled monolayers (SAMs) of thiolates. These films were characterized by polarization modulation Fourier…

Electroanalysis, 2006, 18 (7), pp.684-694. ⟨10.1002/elan.200503451⟩. ⟨inserm-00194708⟩

  • Article dans une revue

Revisiting Acido-basicity of the MgO Surface by Periodic Density Functional Theory Calculations: Role of Surface Topology and Ion Coordination on Water Dissociation

Céline Chizallet, Guylène Costentin, Michel Che, Françoise Delbecq, Philippe Sautet

Low-coordinated (LC) ions at the MgO surface (noted Mg2+ LC and O2- LC with L ) 1-5), located on monatomic and diatomic steps, corners, step divacancies, and kinks, have been modeled thanks to periodic density functional theory (DFT) calculations (VASP). Ions of lowest coordination induce the…

Journal of Physical Chemistry B, 2006, 110, pp.15878-15886. ⟨10.1021/jp060840l⟩. ⟨hal-00112168⟩