Laboratoire de réactivité de surface

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  • Article dans une revue

Lipase-embedded Silica Nanoparticles with Oil-filled Core-Shell Structure: Stable and Recyclable Platforms for Biocatalysts

Yasutaka Kuwahara, Takato Yamanishi, Takashi Kamegawa, Kohsuke Mori, Michel Che, Hiromi Yamashita

Lipase enzyme was embedded within silica nanoparticles with oil-filled core-shell structure. The enzyme embedded within such architecture retained all of its activity and showed high catalytic performance both in water and in organic media with optimal stability and recyclability.

Chemical Communications, 2012, 48, pp.2882-4. ⟨10.1039/c2cc17896f⟩. ⟨hal-00744697⟩

  • Article dans une revue

Amphiphilic block copolymer nano-fibers via RAFT-mediated polymerization in aqueous dispersed system

Stephanie Boisse, Jutta Rieger, Khaled Belal, Aurelie Di-Cicco, Patricia Beaunier, Min-Hui Li, Bernadette Charleux

Self-assembled block copolymer nanofibers are attractive materials for multiple applications. We propose here a novel, very simple and straightforward method to prepare polymeric nanofibers at high solids contents directly in water. It is based on an aqueous emulsion polymerization process…

Chemical Communications, 2010, 46 (11), pp.1950-2 FIELD Reference Number: FIELD Journal Code:9610838 FIELD Call Number:. ⟨10.1039/b923667h⟩. ⟨hal-00604702⟩

  • Article dans une revue

The genesis of a heterogeneous catalyst: in situ observation of a transition metal complex adsorbing onto an oxide surface in solution

Antoine Hervier, Juliette Blanchard, Guylène Costentin, John R. Regalbuto, Catherine Louis, Souhir Boujday

Understanding the interactions between metal complexes and oxide surfaces is crucial to the synthesis of supported metal catalysts. Recently developed in situ techniques have made it possible to closely characterize the solid/liquid interface. For the first time, the adsorption of platinum…

Chemical Communications, 2014, 50, pp.2379-2548. ⟨10.1039/C3CC48838A⟩. ⟨hal-00982311⟩

  • Article dans une revue

Assessing the Oxidation Behavior of EC:DMC Based Electrolyte on Non- Catalytically Active Surface

Iban Azcarate, Wei Yin, Christophe Méthivier, François Ribot, Christel Laberty-Robert, Alexis Grimaud

The race for developing Li-ion batteries positive electrodes with always greater energy density has recently renewed interest towards understanding the formation of the so-called cathode electrolyte interface (CEI) forming upon cycling at high potential. In this work, we used an approach combining…

Journal of The Electrochemical Society, 2020, 167 (8), pp.080530. ⟨10.1149/1945-7111/ab8f57⟩. ⟨hal-02640318⟩

  • Chapitre d'ouvrage

La Recherche en Chimie aux Frontières de la Connaissance

Dominique Massiot, Claire-Marie Pradier, Jacques Maddaluno, Jean-François Tassin, Joël Moreau, Mehran Mostafavi, Anne Imberty, Pascal Breuilles, Catherine Larroche

L’Unité Mixte de Recherche est la brique élémentaire, souple et pérenne d’un paysage de la recherche en évolution rapide. De nombreux dispositifs viennent structurer l’activité de ces équipes pour faire émerger des pôles de recherche, consolider le maillage des réseaux nationaux, identifier les…, Mixed research units are building blocks, flexible but permanent, in rapidly evolving fields of research. Several measures shape the activities of research teams and thus give rise to “poles of research”. They also help consolidate national networks, identify strong points, boost the sharing of top…

L’industrie Chimique : quel avenir en France ?, 2015, Annales des Mines, 2015, Annales des Mines. Réalités Industrielles. ⟨hal-01228736⟩

  • Article dans une revue

On an additional promoting role of hydrogen in the H2-assistedC3H6-SCR of NOxon Ag/Al2O3: A lowering of the temperature offormation-decomposition of the organo-NOxintermediates?

Cyril Thomas

tThe addition of minute amounts of H2to the selective catalytic reduction of nitrogen oxides (NOx)by hydrocarbons (HC-SCR) has been shown to promote the reduction of NOxat remarkably lowerreaction temperatures on Ag/Al2O3catalysts. Despite extensive investigations, the origin of this remark-able…

Applied Catalysis B: Environmental, 2014, 162, pp.454-462. ⟨10.1016/j.apcatb.2014.07.021⟩. ⟨hal-01064983⟩

  • Article dans une revue

Optimization and Antibacterial Response of N-Halamine Coatings Based on Polydopamine

Nadia Nazi, Adeline Marguier, Catherine Debiemme-Chouvy, Vincent Humblot

RessouDue to the ability of microorganisms to first adhere to a material surface and then to lead to the formation of a biofilm, it is essential to develop surfaces that have antimicrobial properties. It is well known that N-halamine coatings allow us to prevent or minimize such phenomena. In the…

Colloids and Interfaces, 2022, 6 (1), pp.9 (20). ⟨10.3390/colloids6010009⟩. ⟨hal-03693047⟩

  • Article dans une revue

Co-grafting of amino-poly(ethylene glycol) and Magainin I on a TiO2 surface: tests of antifouling and antibacterial activities.

Jessie Peyre, V. Humblot, C. Méthivier, J.M. Berjeaud, C.-M. Pradier

An antimicrobial peptide, Magainin I (Mag), was grafted to a titanium oxide surface, via an antiadhesive poly(ethylene glycol) (PEG) cross-linker. The latter plays a 2-fold part, being antiadhesive, and enabling the covalent immobilization of the peptide. The functionalization was characterized at…

Journal of Physical Chemistry B, 2012, 116, pp.13839-47. ⟨10.1021/jp305597y⟩. ⟨hal-00808576⟩

  • Article dans une revue

Heterogeneous partial oxidation catalysis on metal oxides

Jacques C. Védrine, Ioana Fechete

This review paper presents an overview of heterogeneous selective ammoxidation and oxidative dehydrogenation (ODH) of light alkanes, particularly of ethane. The conversion of ethane to ethene is in great demand in the domestic and worldwide chemical industry. The review has been voluntarily…

Comptes Rendus. Chimie, 2016, 19 (10), pp.1203-1225. ⟨10.1016/j.crci.2015.09.021⟩. ⟨hal-01289317⟩

  • Article dans une revue

Building the uracil skeleton in primitive ponds at the origins of life: carbamoylation of aspartic acid

Louis Ter-Ovanessian, Jean-François Lambert, Marie-Christine Maurel

Abstract A large set of nucleobases and amino acids is found in meteorites, implying that several chemical reservoirs are present in the solar system. The “geochemical continuity” hypothesis explores how protometabolic paths developed from so-called “bricks” in an enzyme-free prebiotic world and…

Scientific Reports, 2022, 12 (1), pp.19178. ⟨10.1038/s41598-022-21272-7⟩. ⟨hal-03848150⟩