• Article dans une revue

Speciation of Ruthenium as a Reduction Promoter of Silica-Supported Co Catalysts: A Time-Resolved in Situ XAS Investigation

Jingping Hong, Eric Marceau, Andrei Y. Khodakov, Lucia Gaberová, Anne Griboval-Constant, Jean-Sébastien Girardon, Camille La Fontaine, Valérie Briois

Complete reduction of the metal phase in cobalt-containing catalysts is often difficult to reach and can be promoted by a small amount of noble metals. Because these costly promoters are introduced in a very low quantity, their speciation and their chemical interaction with cobalt have seldom been…

ACS Catalysis, 2015, 5 (2), pp.1273-1282. ⟨10.1021/cs501799p⟩. ⟨hal-01120477⟩

• Article dans une revue

Correction to “Nanosized Layered TOT Magnesium Silicates: Equilibrium Morphologies and Surface Speciation, a Computational and Experimental Study”

Hervé Toulhoat, Longfei Lin, Dalil Brouri, Jean-Marc Krafft, Yannick Millot, Guillaume Laugel, Hélène Lauron-Pernot

Journal of Physical Chemistry C, 2020, 124 (2), pp.1761-1764. ⟨10.1021/acs.jpcc.9b11604⟩. ⟨hal-04031145⟩

• Article dans une revue

Ethylene production from diluted bioethanol solutions

Ilenia Rossetti, Matteo Compagnoni, Giorgia de Guido, Laura A. Pellegrini, Gianguido Ramis, Stanislaw Dzwigaj

Ethylene production by ethanol dehydration has been investigated over a set of zeolites with BEA structure in acidic form (HAlBEA). The effect on Ni addition (up to 0.03 g/g (3 mass%)) is explored as a means to improve ethylene selectivity limiting the formation of heavier byproducts. The reaction…

Canadian Journal of Chemical Engineering, 2017, 95 (9), pp.1752 - 1759. ⟨10.1002/cjce.22828⟩. ⟨hal-01651993⟩

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Factors impacting protein adsorption on layer-by-layer assembled stimuli-responsive thin films

A. Osypova, C.-A. Fustin, C.-M. Pradier, Jessem Landoulsi, S. Demoustier-Champagne

Studying the stimuli-response of polyelectrolyte multilayers (PEMs) towards protein adsorption requires coping with the multiplicity of factors influencing interfacial processes. In this study, we report the design of a nanostructured stimuli-responsive coating based on the sequential layer-by…

European Polymer Journal, 2017, 95, pp.195 - 206. ⟨10.1016/j.eurpolymj.2017.08.019⟩. ⟨hal-01651981⟩

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Structural studies of adsorbed protein (betalactoglobulin) on natural clay (montmorillonite)

Ali Assifaoui, Lucie Huault, Cyrielle Maissiat, Chloé Roullier-Gall, Philippe Jeandet, Jerôme Hirschinger, Jesus Raya, Maguy Jaber, Jean-François Lambert, Philippe Cayot, Régis Gougeon, Camille Loupiac

In this work, the adsorption of a small globular protein (betalactoglobulin, BLG), on a natural montmorillonite clay (Mt) was investigated in acidic buffer (pH = 3). The combination of different characterization techniques such as zetametry, X-ray diffraction, transmission electronic microscopy,…

RSC Advances, 2014, 4 (105), pp.61096-61103. ⟨10.1039/C4RA11607K⟩. ⟨hal-02358967⟩

• Communication dans un congrès

Nouvelles biocathodes graphite/nitrure de carbone amorphe/laccase pour la réduction de l'oxygène par transfert électronique direct

Achraft Blout, Alain Pailleret, Hubert Perrot, Claude Jolivalt

Les enzymes constituent une alternative intéressante aux catalyseurs métalliques car elles possèdent une meilleure sélectivité et des performances catalytiques souvent plus élevées. Elles peuvent être utilisées dans différents types de dispositifs électrochimiques comme les piles à combustible1.…

Journées d'Electrochimie 2017 (JE 2017), Société Chimique de France (SCF), Jun 2017, Bordeaux, France. ⟨hal-03946920⟩

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Transition metal borides of Ni-B (Co-B) as alternative non-precious catalytic materials: Advances, potentials, and challenges. Short review

Marek Lewandowski, Maria Bartoszewicz, Karolina Jaroszewska, Gérald Djéga-Mariadassou

This review gives a brief presentation of the types, structure, synthesis, and application of amorphous transition metal borides (Mt-B) in particular the bulk or supported nickel and cobalt borides (NiB and CoB). Mt-B materials are amorphous metal-metalloid alloys and constitute an important group…

Journal of Industrial and Engineering Chemistry, 2022, 116, pp.75-98. ⟨10.1016/j.jiec.2022.09.031⟩. ⟨hal-04030854⟩

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EIS investigation of zinc dissolution in aerated sulphate medium. Part II: zinc coatings

Chantal Cachet, F. Ganne, Suzanne Joiret, Georges Maurin, J. Petitjean, Vincent Vivier, Robert Wiart

The kinetics of anodic dissolution and corrosion of zinc coatings deposited onto steel sheet either by electrodeposition or by hot dipping are investigated by electrochemical impedance spectroscopy in aerated sulfate medium. The results are compared with those obtained previously on pure bulk zinc…

Electrochimica Acta, 2002, 47 (21), pp.3409-3422. ⟨10.1016/S0013-4686(02)00277-3⟩. ⟨hal-04219844⟩

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Selective Catalytic Reduction of NO x over Au/Al2O3: Influence of the Gold Loading on the Promoting Effect of H2 in H2-Assisted C3H6-SCR of NO x

Tesnim Chaieb, Cyril Thomas, Sandra Casale, Catherine Louis, Laurent Delannoy

This article reports on the promotional effect of adding H2 to the reaction feed for the selective catalytic reduction of NO x with propene (H2–C3H6-SCR) over Au/Al2O3 catalysts. For this purpose, the influence of the Au loading in H2–C3H6-SCR was investigated. The H2 promoting effect in C3H6-SCR,…

Catalysis Letters, 2018, 148 (2), pp.539 - 546. ⟨10.1007/s10562-017-2276-1⟩. ⟨hal-01740051⟩

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Dual Thermo- and pH-Responsive N -Cyanomethylacrylamide-Based Nano-Objects Prepared by RAFT-Mediated Aqueous Polymerization-Induced Self-Assembly

Nicolas Audureau, Fanny Coumes, Jean-Michel Guigner, Clément Guibert, François Stoffelbach, Jutta Rieger

We report the straightforward synthesis of dual stimuli-responsive nano-objects using a RAFT-mediated polymerization-induced self-assembly (PISA) process in water. The key to complex and tunable responsiveness was the copolymerization of N-cyanomethylacrylamide, providing UCST-type polymers, with a…

Macromolecules, 2022, 55 (24), pp.10993-11005. ⟨10.1021/acs.macromol.2c01953⟩. ⟨hal-03988200⟩