Laboratoire de réactivité de surface

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  • Article dans une revue

Identification of iron species in FeSiBEA by DR UV-vis, XPS and Mössbauer spectroscopy: Influence of Fe content

J. Gurgul, K. Łątka, I. Hnat, J. Rynkowski, S. Dzwigaj

The nature of iron in FeSiBEA zeolite was identified using DR UV-vis, XPS and Mössbauer spectroscopy. Various FexSiBEA zeolites (x = 3.8, 8.2 and 15 wt.%) were prepared by a two-step post synthesis method, which consisted in the creation of vacant T-atom sites by dealumination of tetraethylammonium…

Microporous and Mesoporous Materials, 2013, 168, pp.1-6. ⟨10.1016/j.micromeso.2012.09.015⟩. ⟨hal-00812092⟩

  • Article dans une revue

On the kinetics of CO oxidation by O2 over RhI(CO)2 catalytic species anchored to a zeolitic support

Céline Fontaine-Gautrelet, Cyril Thomas, Jean-Marc Krafft, Gérald Djéga-Mariadassou

The reactivity of RhI(CO)2 towards CO oxidation was studied on a model Rh(0.7 wt%)/HY material. The kinetic results show that RhI(CO)2 exhibit a fairly low activity. It is therefore suggested that the catalytic species responsible for the enhanced activity of Rh/Ce0.68Zr0.32O2 [Manuel et al., J.…

Topics in Catalysis, 2007, 42-43, pp.357-361. ⟨10.1007/s11244-007-0205-z⟩. ⟨hal-00157007⟩

  • Article dans une revue

Surface response methodology for the study of supported membrane formation.

C. Rossi, Elisabeth Briand, P. Parot, Michaël Odorico, Joël Chopineau

We report on the investigations of the formation of the tethered lipid bilayer by vesicle deposition on amine-functionalized surfaces. The tethered bilayer was created by the deposition of egg-PC vesicles containing 1,2-distearoyl-sn-glycero-3-phosphoethanolamine-poly-(ethyleneglycol)-N-…

Journal of Physical Chemistry B, 2007, 111, pp.7567-7576. ⟨10.1021/jp0686792⟩. ⟨hal-00172758⟩

  • Article dans une revue

A comparative in situ TEM and UV-visible spectroscopic study of the thermal evolution of Ag species dispersed on Al2O3 and NaX zeolite supports

Elie Sayah, Dalil Brouri, Pascale Massiani

The oxidation states and dispersion of silver supported on alumina and faujasite were monitored by TEM, TPR and in situ UV-visible spectroscopy along the steps of thermal dehydration, then oxidation and finally reduction of the freshly prepared materials. An original transmission electron…

Catalysis Today, 2013, 218-219, pp.10-17. ⟨10.1016/j.cattod.2013.06.003⟩. ⟨hal-00958109⟩

  • Article dans une revue

Catalytic activity of HAlBEA and NixHAlBEA zeolites in hydrogen-assisted dehydrochlorination of 1,2-dichloroethane into vinyl chloride monomer

Rafal Baran, Anna Srebowata, I.I. Kaminska, D. Łomot, Stanislaw Dzwigaj

HAlBEA zeolite is prepared by calcination of parent TEABEA zeolite at 823 K for 3 h in air following ionic exchange with NH4NO3 solution. NixHAlBEA zeolites are prepared by impregnation of HAlBEA with an aqueous solution of Ni(NO3)2, following a drying at 333 K to obtain NixHAlBEA. The calcination…

Microporous and Mesoporous Materials, 2013, 180, pp.209-218. ⟨10.1016/j.micromeso.2013.06.037⟩. ⟨hal-00910991⟩

  • Article dans une revue

Exploring the self-assembly of dumbbell-shaped polyoxometalate hybrids, from molecular building units to nanostructured soft materials

Mireia Segado Centellas, Madeleine Piot, Raphaël Salles, Anna Proust, Ludovic Tortech, Dalil Brouri, Sébastien Hupin, Benjamin Abécassis, David Landy, Carles Bo, Guillaume Izzet

The formation of hierarchical nanostructures using preformed dumbbell-like species made of covalent organic–inorganic polyoxometalate (POM)-based hybrids is herein described. In this system, the presence of charged subunits (POM, metal linkers, and counter ions) in the complex molecular…

Chemical Science, 2020, 11 (40), pp.11072 - 11080. ⟨10.1039/D0SC03243C⟩. ⟨hal-02954983⟩

  • Article dans une revue

Insight into the mechanism of action of temporin-SHa, a new broad-spectrum antiparasitic and antibacterial agent

Zahid Raja, Sonia André, Feten Abbassi, Vincent Humblot, Olivier Lequin, Tahar Bouceba, Isabelle Correia, Sandra Casale, Thierry Foulon, Denis Sereno, Bruno Oury, Ali Ladram

Antimicrobial peptides (AMPs) are promising drugs to kill resistant pathogens. In contrast to bacteria, protozoan parasites, such as Leishmania, were little studied. Therefore, the antiparasitic mechanism of AMPs is still unclear. In this study, we sought to get further insight into this mechanism…

PLoS ONE, 2017, 12 (3), pp.e0174024. ⟨10.1371/journal.pone.0174024⟩. ⟨hal-01517346⟩

  • Article dans une revue

Potent antimicrobial peptides against Legionella pneumophila and its environmental host, Acanthamoeba castellanii.

Margot Schlusselhuber, Vincent Humblot, Sandra Casale, Christophe Méthivier, Julien Verdon, Matthias Leippe, Jean-Marc Berjeaud

Legionella pneumophila, the major causative agent of Legionnaires' disease, is most often found in the environment in close association with free-living amoebae, leading to persistence, spread, biocide resistance, and elevated virulence of the bacterium. In the present study, we evaluated the…

Applied Microbiology and Biotechnology, 2015, 99 (11), pp.4879-91. ⟨10.1007/s00253-015-6381-z⟩. ⟨hal-01427428⟩

  • Article dans une revue

Amplified plasmonic detection of DNA hybridization using doxorubicin-capped gold particles

Jolanda Spadavecchia, Ramesh Perumal, Alexandre Barras, Joël Lyskawa, Patrice Woisel, William Laure, Claire-Marie Pradier, Rabah Boukherroub, Sabine Szunerits

We show in this article that doxorubicin-modified gold nanoparticles (Au NP-DOX) can be used for the post-amplification of the wavelength shift of localized surface plasmon resonance (LSPR) signals after DNA hybridization events. We take advantage of the intercalation properties of DOX with guanine…

Analyst, 2013, 139, pp.157-164. ⟨10.1039/c3an01794j⟩. ⟨hal-01044451⟩

  • Article dans une revue

Influence of the nature and environment of manganese in Mn-BEA zeolites on NO conversion in selective catalytic reduction with ammonia

Rafal Baran, L. Valentin, J.-M. Krafft, T. Grzybek, P. Glatzel, Stanislaw Dzwigaj

Manganese-containing BEA zeolites, MnxSiBEA (x = 1–4 wt %) and Mn(I.E.)AlBEA, were prepared by a two-step postsynthesis method and a conventional wet ion-exchange, respectively, and applied as catalysts in the selective catalytic reduction of NO with ammonia (NH3-SCR). The physicochemical analysis…

Physical Chemistry Chemical Physics, 2017, 176 (1), pp.229-233. ⟨10.1039/C7CP02096A⟩. ⟨hal-01527245⟩