• Article dans une revue

A Study of Cobalt Speciation in Co/Al2O3 Catalysts Prepared from Solutions of Cobalt-Ethylenediamine Complexes

François Dumond, Eric Marceau, Michel Che

The thermal reduction of Co/Al2O3 catalysts prepared by impregnation of Co(II) nitrate generally leads to migration of cobalt ions into alumina with formation of cobalt aluminate. In order to prevent the latter, it is attempted to reduce cobalt by decomposition of supported precursor salts…

Journal of Physical Chemistry C, 2007, 111 (12), pp.4780-4789. ⟨10.1021/jp067781w⟩. ⟨hal-00143721⟩

• Article dans une revue

Influence of the pretreatment conditions on the performances of CeO2-supported gold catalysts in the Catalytic Wet Air Oxidation of carboxylic acids

Ngoc D. Tran, Michèle Besson, Claude Descorme, Katia Fajerwerg, Catherine Louis

Two series of ceria-supported gold catalysts (1 and 4 wt.% Au) were prepared by deposition-precipitation with urea. Depending on the gold loading, the pretreatment of the Au/CeO2 catalysts (calcination in air vs. reduction in hydrogen) had a great influence on the oxidation state of gold, and in…

Catalysis Communications, 2011, 16, pp.98-102. ⟨10.1016/j.catcom.2011.09.014⟩. ⟨hal-00666922⟩

• Article dans une revue

Selective Modification of the Acid-Base Properties of Ceria by Supported Au

Manuela C.I. Bezen, Cornelia Breitkopf, Nadia El Kolli, Jean-Marc Krafft, Catherine Louis, J.A. Lercher

Au supported on CeO2 prepared by deposition-precipitation with urea leads to a basic catalyst. Au acts in two ways as surface modifier. First, Au selectively interacts with Ce4+ cations by either blocking access to or reducing Ce4+ to Ce3+. Second, the resulting Au atoms (presumably as Au+ ions)…

Chemistry - A European Journal, 2011, 17 (25), pp.7095-7104. ⟨10.1002/chem.201002011⟩. ⟨hal-00666903⟩

• Article dans une revue

Comparison of competition between T = O and T-OH groups in vanadium, niobium, tantalum BEA zeolite and SOD based zeolites

Anna Wojtszek, Maria Zioleck, Stanislaw Dzwigaj, Frederik Tielens

The investigation of intra framework substitution of Si by group V transition metals (V, Nb, Ta) is an important strategy to modify or to tune the catalytic properties of zeolites. Theoretically one of the limitations is the size of the zeolite unit cell. In this study the energy and geometry of…

Chemical Physics Letters, 2011, 514, pp.70-73. ⟨10.1016/j.cplett.2011.08.005⟩. ⟨hal-00666258⟩

• Article dans une revue

Kinetic effects in dehydration, rehydration, and isotopic exchange of bacterial photosynthetic reaction centers

Marco Malferrari, Francesco Francia, Alberto Mezzetti, Giovanni Venturoli, Klaus Gerwert

BACKGROUND:In IR difference spectroscopy of proteins and biological systems, as in many other biophysical techniques, experiments at different hydration levels, and after H/D or H216O/H218O exchange are particularly important, for band assignment and for mechanistic studies. OBJECTIVE:Evaluate the…

Biomedical Spectroscopy and Imaging, 2016, 5 (2), pp.185 - 196. ⟨10.3233/BSI-160136⟩. ⟨hal-01547861⟩

• Article dans une revue

Biomineralization Patterns of Intracellular Carbonatogenesis in Cyanobacteria: Molecular Hypotheses

Jinhua Li, Isabel Margaret-Oliver, Nithavong Cam, Thomas Boudier, Marine Blondeau, Eric Leroy, Julie Cosmidis, Feriel Skouri-Panet, Jean-Michel Guigner, Céline Férard, Melanie Poinsot, David Moreira, Purificacion Lopez-Garcia, Corinne Cassier-Chauvat, Franck Chauvat, Karim Benzerara

The recent discovery of intracellular carbonatogenesis in several cyanobacteria species has challenged the traditional view that this process was extracellular and not controlled. However, a detailed analysis of the size distribution, chemical composition and 3-D-arrangement of carbonates in these…

Minerals, 2016, 6 (1), pp.10. ⟨10.3390/min6010010⟩. ⟨hal-01310553⟩

• Article dans une revue

Time-resolved infrared spectroscopy in the study of photosynthetic systems.

Alberto Mezzetti, Winfried Leibl

Time-resolved (TR) infrared (IR) spectroscopy in the nanosecond to second timescale has been extensively used, in the last 30 years, in the study of photosynthetic systems. Interesting results have also been obtained at lower time resolution (minutes or even hours). In this review, we first…

Photosynthesis Research, 2017, 131 (2), pp.121-144. ⟨10.1007/s11120-016-0305-3⟩. ⟨hal-01451714⟩

• Article dans une revue

BSA and lysozyme adsorption on homoionic montmorillonite: Influence of the interlayer cation

Mathilde Lepoitevin, Maguy Jaber, Régis Guégan, Jean-Marc Janot, Philippe Dejardin, Francois Henn, Sébastien Balme

This study aims to investigate the influence of interlayer cation alkali metal series (Li+, Na+, K+, Rb+, Cs+) and alkali earth metal (Mg2 +, Ca2 +, Ba2 +) on adsorption of model proteins (lysozyme and bovine serum albumin). The localizations of both proteins and their conformational modifications…

Applied Clay Science, 2014, 95, pp.396-402. ⟨10.1016/j.clay.2014.05.003⟩. ⟨insu-01017005⟩

• Article dans une revue

Gold, Silver, and Iron Oxide Nanoparticle Incorporation into Silk Hydrogels for Biomedical Applications: Elaboration, Structure, and Properties

Cristina Belda Marín, Christophe Egles, Vincent Humblot, Yoann Lalatonne, Laurence Motte, Jessem Landoulsi, Erwann Guénin

Silk fibroin (SF) is a versatile material with biodegradable and biocompatible properties, which make it fit for broad biomedical applications. In this context, the incorporation of nanosized objects into SF allows the development of a variety of bionanocomposites with tailored properties and…

ACS Biomaterials Science and Engineering, 2021, 7 (6), pp.2358-2371. ⟨10.1021/acsbiomaterials.1c00441⟩. ⟨hal-03366494⟩

• Article dans une revue

Recent developments and prospectives of acid-base and redox catalytic processes by metal oxides

Jacques C. Védrine

Applied Catalysis A : General, 2019, 575, pp.170 - 179. ⟨10.1016/j.apcata.2019.02.012⟩. ⟨hal-03485895⟩