Laboratoire de réactivité de surface

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  • Article dans une revue

Exploring the self-assembly of dumbbell-shaped polyoxometalate hybrids, from molecular building units to nanostructured soft materials

Mireia Segado Centellas, Madeleine Piot, Raphaël Salles, Anna Proust, Ludovic Tortech, Dalil Brouri, Sébastien Hupin, Benjamin Abécassis, David Landy, Carles Bo, Guillaume Izzet

The formation of hierarchical nanostructures using preformed dumbbell-like species made of covalent organic–inorganic polyoxometalate (POM)-based hybrids is herein described. In this system, the presence of charged subunits (POM, metal linkers, and counter ions) in the complex molecular…

Chemical Science, 2020, 11 (40), pp.11072 - 11080. ⟨10.1039/D0SC03243C⟩. ⟨hal-02954983⟩

  • Article dans une revue

Synthesis of Well-Defined Dawson-Type Poly(N,N-diethylacrylamide) Organopolyoxometalates

Jennifer Lesage de la haye, Patricia Beaunier, Laurent Ruhlmann, Bernold Hasenknopf, Emmanuel Lacôte, Jutta Rieger

An organotin-substituted Dawson-type phosphotungstate was covalently linked to a trithiocarbonate group by postfunctionalization methods. This organopolyoxometalate led to a series of polyoxometalate (POM)–poly(N,N-diethylacrylamide) hybrids in a controlled way through reversible addition–…

ChemPlusChem, 2014, 79 (2), pp.250-256. ⟨10.1002/cplu.201300346⟩. ⟨hal-01121569⟩

  • Article dans une revue

A MSFD complementary approach for the assessment of pressures, knowledge and data gaps in Southern European Seas: The PERSEUS experience

A. Crise, H. Kaberi, J. Ruiz, A. Zatsepin, E. Arashkevich, M. Giani, A.P. Karageorgis, L. Prieto, M. Pantazi, D. Gonzalez-Fernandez, M. Ribera D’alcalà, V. Tornero, V. Vassilopoulou, Xavier Durrieu de Madron, Cecile Guieu, P. Puig, A. Zenetos, B. Andral, D. Angel, D. Altukhov, Sakina-Dorothée Ayata, Y. Aktan, E. Balcioğlu, Fabio Benedetti, M. Bouchoucha, M.-C. Buia, J.-F. Cadiou, M. Canals, M. Chakroun, E. Christou, M.G. Christidis, G. Civitarese, V. Coatu, M. Corsini-Foka, S. Cozzi, A. Deidun, A. Dell’aquila, A. Dogrammatzi, C. Dumitrache, D. Edelist, O. Ettahiri, S. Fonda-Umani, S. Gana, F. Galgani, Stéphane Gasparini, A. Giannakourou, M.-T. Gomoiu, A. Gubanova, A.-C. Gücü, Ö. Gürses, G. Hanke, I. Hatzianestis, B. Herut, R. Hone, E. Huertas, J.-O. Irisson, M. İşinibilir, Julie Jimenez, S. Kalogirou, K. Kapiris, V. Karamfilov, S. Kavadas, Ç. Keskin, A.E. Kideyş, M. Kocak, G. Kondylatos, C. Kontogiannis, R. Kosyan, P. Koubbi, G. Kušpilić, R. La Ferla, L. Langone, S. Laroche, L. Lazar, E. Lefkaditou, I.E. Lemeshko, A. Machias, A. Malej, M.-G. Mazzocchi, V. Medinets, N. Mihalopoulos, S. Miserocchi, S. Moncheva, V. Mukhanov, G. Oaie, A. Oros, A.A. Öztürk, B. Öztürk, M. Panayotova, A. Prospathopoulos, G. Radu, V. Raykov, P. Reglero, G. Reygondeau, N. Rougeron, B. Salihoglu, A. Sanchez-Vidal, G. Sannino, C. Santinelli, D. Secrieru, G. Shapiro, N. Simboura, T. Shiganova, M. Sprovieri, K. Stefanova, N. Streftaris, V. Tirelli, M. Tom, B. Topaloğlu, N.E. Topçu, K. Tsagarakis, C. Tsangaris, G. Tserpes, S. Tuğrul, Z. Uysal, D. Vasile, K. Violaki, J. Xu, A. Yüksek, E. Papathanassiou

PERSEUS project aims to identify the most relevant pressures exerted on the ecosystems of the Southern European Seas (SES), highlighting knowledge and data gaps that endanger the achievement of SES Good Environmental Status (GES) as mandated by the Marine Strategy Framework Directive (MSFD). A…

Marine Pollution Bulletin, 2015, 95 (1), pp.28-39. ⟨10.1016/j.marpolbul.2015.03.024⟩. ⟨hal-01169407⟩

  • Article dans une revue

Surface segregation in AuPd alloys: Ab initio analysis of the driving forces

Jérôme Creuze, Hazar Guesmi, Christine Mottet, Beien Zhu, Bernard Legrand

In order to determine the energetic driving forces for surface segregation in AuPd alloys, we use a combined approach coupling ab initio calculations and an analysis via an effective Ising model. Previously, this approach has been used successfully in the framework of N-body interatomic potentials…

Surface Science : A Journal Devoted to the Physics and Chemistry of Interfaces, 2015, 639, pp.48 - 53. ⟨10.1016/j.susc.2015.04.017⟩. ⟨hal-01378430⟩

  • Article dans une revue

Structure, Orientation and Stability of Lysozyme Confined in layered Materials

Sébastien Balme, Régis Guégan, Jean-Marc Janot, Maguy Jaber, Mathilde Lepoitevin, Philippe Dejardin, Xavier Bourrat, Mikael Motelica-Heino

The confinement of lysozyme in 3 layered materials based on montmorillonite and lamellar double hydroxide exhibiting different surface charges was studied. The protein structure and orientation in these materials were determined by X-Ray diffraction, time resolved fluorescence and fluorescence…

The Royal Society of Chemistry, 2013, 9 (11), pp.3188-3196. ⟨10.1039/C3SM27880H⟩. ⟨insu-00779421v2⟩

  • Communication dans un congrès

Heterogeneous Fenton-like reactions in natural soils and sediments at neutral pH with O2 as oxidant

Elora Bourbon, Frederic Averseng, Thierry Allard, Pierre Le Pape, Sylvie Nélieu, Xavier Carrier, Guillaume Morin, Elodie Guigon, Fulvia Baratelli, Sophie Ayrault

Heterogeneous Fenton-like processes using O2 as oxidant and iron(II) minerals as substrate is a rapidly growing research field with important implications especially for in-situ organic pollutant degradation in natural media. These reactions can be conducted at neutral pH and several minerals are…

Goldschmidt 2023, Jul 2023, Lyon, France. ⟨hal-04390051⟩

  • Article dans une revue

Production of Laccase by Recombinant Yarrowia lipolytica from Molasses: Bioprocess Development Using Statistical Modeling and Increase Productivity in Shake-Flask and Bioreactor Cultures

Farshad Darvishi, Marzieh Moradi, Catherine Madzak, Claude Jolivalt

Laccases are used in numerous applications, from green degradation of various xenobiotic compounds, waste detoxification, textile dye bleaching, and delignification of lignocellulose materials to biofuel production. In this study, the recombinant Yarrowia lipolytica YL4 strain carrying the white-…

Applied Biochemistry and Biotechnology, 2017, 181 (3), ⟨10.1007/s12010-016-2280-8⟩. ⟨hal-01531721⟩

  • Article dans une revue

Amplified plasmonic detection of DNA hybridization using doxorubicin-capped gold particles

Jolanda Spadavecchia, Ramesh Perumal, Alexandre Barras, Joël Lyskawa, Patrice Woisel, William Laure, Claire-Marie Pradier, Rabah Boukherroub, Sabine Szunerits

We show in this article that doxorubicin-modified gold nanoparticles (Au NP-DOX) can be used for the post-amplification of the wavelength shift of localized surface plasmon resonance (LSPR) signals after DNA hybridization events. We take advantage of the intercalation properties of DOX with guanine…

Analyst, 2013, 139, pp.157-164. ⟨10.1039/c3an01794j⟩. ⟨hal-01044451⟩

  • Article dans une revue

Influence of the nature and environment of manganese in Mn-BEA zeolites on NO conversion in selective catalytic reduction with ammonia

Rafal Baran, L. Valentin, J.-M. Krafft, T. Grzybek, P. Glatzel, Stanislaw Dzwigaj

Manganese-containing BEA zeolites, MnxSiBEA (x = 1–4 wt %) and Mn(I.E.)AlBEA, were prepared by a two-step postsynthesis method and a conventional wet ion-exchange, respectively, and applied as catalysts in the selective catalytic reduction of NO with ammonia (NH3-SCR). The physicochemical analysis…

Physical Chemistry Chemical Physics, 2017, 176 (1), pp.229-233. ⟨10.1039/C7CP02096A⟩. ⟨hal-01527245⟩

  • Article dans une revue

Importance, features and uses of metal oxide catalysts in heterogeneous catalysis

Jacques C. Védrine

This short review paper aims at assembling the present state of the art of the multiuses of metal oxides in heterogeneous catalysis, concerning liquid and gaseous phases of the reactant mixtures on solid catalysts. It includes the description of the main types of metal oxide catalysts, of their…

Chinese Journal of Catalysis, 2019, 40 (11), pp.1627-1636. ⟨10.1016/S1872-2067(18)63162-6⟩. ⟨hal-02405087⟩